Nanocrystalline carbon nitride films were synthesized on cobalt-covered Si(111) wafers using a nitrogen-atom-beam-assisted pulsed laser ablation method. Raman spectroscopy and other analyses showed that as-synthesized films were constructed primarily from nanometer-sized and crystallites. Catalyzation by the cobalt in the synthesis process is considered to play an important role in the formation of nanocrystalline The effect of the experimental conditions on the characters of the as-synthesized films has been discussed.
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