The X‐band conduction electron quantum interference and its transport through Γ virtual state were observed in the AlxGa1−xAs/AlAs/AlxGa1−xAs/AlAs/AlxGa1−xAs heterostructures with x=0.42, 0.45, and 0.5. Due to the existence of the deep donors, the carriers in AlxGa1−xAs electrodes were frozen out at low temperature, and the current‐voltage (IV) characteristics could only be measured under illumination. For x=0.45 and 0.5, the interference patterns were clearly observed in the differential conductance (dI/dV) versus voltage plot at 8.2 K and they disappear at about 15 K for x=0.45 and 25 K for x=0.5. For x=0.42, however, the interference pattern is seen only in the d2I/dV2 vs V characteristics under low carrier concentration. The observation of this quantum interference effect leads to the conclusions that the scattering rate for X‐band electrons in AlxGa1−xAs was 1.13×1012 s−1 at 25 K for x=0.5 and 8.75×1011 s−1 at 15 K for x=0.45, respectively. For x=0.42, the scattering events at 8.2 K were dominated by electron–electron and X–Γ intervalley scattering.

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