This paper presents the solution of the materials characterization problem in which the elastic constants of an anisotropic material are determined from ultrasonic wavespeed measurements made in nonprincipal directions of a specimen. The ultrasonic waves were generated via the pointsource/pointreceiver technique using a pulsed laser as a source and a miniature, point‐like transducer as a receiver. Data were acquired during a scan of the source along one of the principal acoustic axes of symmetry of the material. In each waveform the arrivals of the quasi‐longitudinal and the two quasi‐shear bulk modes were measured and the elastic constants of the material were then recovered using an optimization algorithm. Experimental results are presented for a transversely isotropic, unidirectional fiberglass/polyester and a single crystal specimen of silicon. It was found that the nonlinear fit between the measured and the recovered longitudinal slowness values is excellent. Some discrepancies are observed in the data for the two shear modes. These are shown to be related to the complexity of the detected signals.

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