Ferroelectric PLZT thin films were prepared onto Pt and fused‐quartz substrates by the rf sputtering method using powder targets with a few wt% of excess PbO. The structures of films were analyzed by x‐ray diffraction and classified into three types depending on substrate temperatures: the perovskite type (PLZT); the pyrochlore type, and the coexistence of both types. For the preparation of PLZT thin films, the substrate temperature was kept above 550 °C. Excess PbO seemed to act as a flux for crystal growth. The Curie temperature and hysteresis loops of thin films were investigated and it was confirmed that ferroelectric PLZT thin films could be obtained without annealing.
REFERENCES
1.
2.
W. J.
Takei
, N. P.
Formigoni
, and M. H.
Francombe
, Appl. Phys. Lett.
15
, 256
(1969
).3.
4.
H.
Matsunami
, M.
Suzuki
, M.
Ishida
, and T.
Tanaka
, Jpn. J. Appl. Phys.
15
, 1163
(1976
).5.
K.
Tanaka
, Y.
Higuma
, K.
Yokoyama
, T.
Nakagawa
, and Y.
Hamakawa
, Jpn. J. Appl. Phys.
15
, 1381
(1976
).6.
7.
8.
This content is only available via PDF.
© 1977 American Institute of Physics.
1977
American Institute of Physics
You do not currently have access to this content.