Numerous techniques and technologies have been proposed for the detection and identification of hazardous chemicals that can harm the lungs and respiratory system as well as the central nervous system and kidneys when inhaled. Most practical techniques can be carried out by extraordinary professionals in well-equipped facilities. A reliable, simple, highly sensitive, and feasible sensing technique is still required. A potential sensor for these harmful chemicals is the photonic crystal fiber (PCF), which achieves several unique properties. A square-core PCF sensor is proposed in this work for the detection of detrimental gases (tetra-chloro silane, tetra-chloro methane, turpentine, and tin terra-chloride) in the THz region. The cladding region is divided into three rings, and each ring has rectangular and square air holes. Within the operating region, we have found a relatively high sensitivity of 96.185% along with 95.407% core power fraction, 0.2211 numerical aperture, and a low effective area of 154 470 μm2 at 1.9 THz frequency. Ignorable confinement loss of 3.071 × 10−14 cm−1 and effective material loss of 0.007 72 cm−1 have been also found. Additionally, the current manufacturing techniques guarantee the viability of the proposed PCF sensor’s manufacture. These obtained results demonstrate that the proposed sensor can be effectively employed for applications involving hazardous chemical compounds, gases, and biosensing.

1.
P.
Fraser
, “
Chemistry of stratospheric ozone and ozone depletion
,”
Aust. Meteorol. Mag.
46
(
3
),
185
193
(
1997
).
2.
A. R. J.
Genge
,
W.
Levason
,
R.
Patel
et al, “
Hydrates of tin tetrachloride
,”
Acta Crystallogr. Sect. C
60
(
4
),
i47
i49
(
2004
).
3.
A. B.
Gomez
,
S.
Rubio
, and
D. P.
Bendito
, “
Analytical methods for the determination of bisphenol A in food
,”
J. Chromatogr. A
1216
(
3
),
449
469
(
2009
).
4.
R. H.
Jibon
,
A. A. M.
Bulbul
, and
M. E.
Rahaman
, “
Numerical investigation of the optical properties for multiple PCF structures in the THz regime
,”
Sens. Bio-Sens. Res.
32
,
100405
(
2021
).
5.
R. H.
Jibon
,
M.
Ahmed
,
M. E.
Rahaman
,
M. K.
Hasan
,
M. M.
Shaikh
, and
A.
Tooshil
, “
Nicotine sensing by photonic crystal fiber in THz regime
,” in
2nd International Conference on Robotics, Electrical and Signal Processing Techniques
(
IEEE ASME Trans. Mechatron
,
2021
), pp.
337
340
.
6.
A. A. M.
Bulbul
,
R. H.
Jibon
,
S.
Biswas
,
S. T.
Pasha
, and
M. A.
Sayeed
, “
Photonic crystal fiber-based blood components detection in THz regime design and simulation
,”
Sens. Int.
2
,
100081
(
2021
).
7.
A. A. M.
Bulbul
,
R. H.
Jibon
,
S. K.
Das
,
T.
Roy
,
A.
Saha
, and
M. B.
Hossain
, “
PCF based formalin detection by exploring the optical properties in THz regime
,”
Nanosci. Nanotech. Asia
11
(3),
314
321
(
2021
).
8.
R. H.
Jibon
,
M.
Ahmed
, and
M. K.
Hasan
, “
Identification of detrimental chemicals of plastic products using PCF in the THz regime
,”
Meas. Sens.
17
,
100056
(
2021
).
9.
M. S.
Hossain
,
S.
Sen
, and
M. M.
Hossain
, “
Design of a chemical sensing circular photonic crystal fiber with high relative sensitivity and low confinement loss for terahertz (THz) regime
,”
Optik
222
,
165359
(
2020
).
10.
S.
Sen
,
M.
Abdullah-Al-Shafi
,
A. S.
Sikder
,
M. S.
Hossain
, and
M. M.
Azad
, “
Zeonex based decagonal photonic crystal fiber (D-PH CF) in the terahertz (THz) band for chemical sensing applications
,”
Sens. Bio-Sens. Res.
31
,
100393
(
2021
).
11.
M. I.
Islam
,
K.
Ahmed
,
M. S.
Islam
,
B. K.
Paul
,
S.
Sen
,
S.
Chowdhury
,
S.
Asaduzzaman
,
A. N.
Bahar
, and
M. B. A.
Miah
, “
Single-mode spiral shape fiber based liquid sensor with ultra-high sensitivity and ultra-low loss: Design and analysis
,”
Karbala Int. J. Mod. Sci.
3
(
3
),
131
142
(
2017
).
12.
A.
Upadhyay
,
S.
Singh
,
D.
Sharma
, and
S. A.
Taya
, “
A comprehensive study of large negative dispersion and highly nonlinear perforated core PCF: theoretical insight
,”
Phys. Scr.
97
,
065504
(
2022
).
13.
S.
Sen
and
K.
Ahmed
, “
Design of terahertz spectroscopy based optical sensor for chemical detection
,”
SN Appl. Sci.
1
,
1215
(
2019
).
14.
S.
Sen
,
S.
Chowdhury
,
K.
Ahmed
, and
S.
Asaduzzaman
, “
Design of a porous cored hexagonal photonic crystal fiber based optical sensor with high relative sensitivity for lower operating wavelength
,”
Photonic Sens.
7
(
1
),
55
65
(
2017
).
15.
S.
Chowdhury
,
S.
Sen
,
K.
Ahmed
,
B. K.
Paul
,
M. B. A.
Miah
,
S.
Asaduzzaman
,
M. S.
Islam
, and
M. I.
Islam
, “
Porous shaped photonic crystal fiber with strong confinement field in sensing applications: Design and analysis
,”
Sens. Bio-Sens. Res.
13
,
63
69
(
2017
).
16.
B. K.
Paul
,
K.
Ahmed
,
D.
Vigneswaran
,
S.
Sen
, and
M. S.
Islam
, “
Quasi photonic crystal fiber for chemical sensing purpose in the terahertz regime design and analysis
,”
Opt. Quant. Electron.
51
(
7
),
1
12
(
2019
).
17.
M.
Yin
,
S.
Tang
, and
M.
Tong
, “
The application of terahertz spectroscopy to liquid petrochemicals detection a review
,”
Appl. Spectrosc. Rev.
51
(
5
),
379
396
(2016).
18.
M. E.
Rahaman
,
R. H.
Jibon
,
H. S.
Mondal
,
M. B.
Hossain
,
A. A. M.
Bulbul
, and
R.
Saha
, “
Design and optimization of a PCF-based chemical sensor in THz regime
,”
Sens. Bio-Sens. Res.
32
,
100422
(
2021
).
19.
S.
Mohamed Nizar
,
E.
Caroline
, and
P.
Krishnan
, “
Design and investigation of a high-sensitivity PCF sensor for the detection of sulfur dioxide
,”
Plasmonics
16
,
2155
2165
(
2021
).
20.
J. N.
Dash
and
R.
Jha
, “
Highly sensitive side-polished birefringent PCF-based SPR sensor in near IR
,”
Plasmonics
11
,
1505
1509
(
2016
).
21.
H.
Liang
,
Y.
Feng
,
H.
Liu
et al, “
High-performance PCF-SPR sensor coated with Ag and graphene for humidity sensing
,”
Plasmonics
17
,
1765
1773
(
2022
).
22.
M. S.
Hossain
and
S.
Sen
, “
Design and performance improvement of optical chemical sensor based photonic crystal fiber (PCF) in the terahertz (THz) wave propagation
,”
Silicon
13
,
3879
3887
(
2021
).
23.
V.
Kaur
and
S.
Singh
, “
Extremely sensitive multiple sensing ring PCF sensor for lower indexed chemical detection
,”
Sens. Bio-Sens. Res.
15
,
12
16
(
2017
).
24.
M.
Niger
and
T. F.
Hasin
, “
Detection of harmful chemical compounds in plastics with highly sensitive photonic crystal fiber with higher nonlinear coefficient
,” in
International Conference on Signal Processing, Information, Communication and Systems
(
IEEE
,
2019
), pp.
18
22
.
25.
M. I.
Islam
,
K.
Ahmed
,
S.
Sen
,
S.
Chowdhury
,
B. K.
Paul
,
M. S.
Islam
,
M. B. A.
Miah
, and
S.
Asaduzzaman
, “
Design and optimization of photonic crystal fiber based sensor for gas condensate and air pollution monitoring
,”
Photonic Sens.
7
(
3
),
234
245
(
2017
).
26.
J. M.
Molina
,
I. J.
Díaz
,
M. F.
Ferńandez
,
A. R.
Carrillo
,
F. M.
Peinado
,
V.
Mustieles
,
R.
Barouki
,
C.
Piccoli
,
N.
Olea
, and
C.
Freire
, “
Determination of bisphenol A and bisphenol S concentrations and assessment of estrogen-and antiandrogen-like activities in thermal paper receipts from Brazil, France, and Spain
,”
Environ. Res.
170
,
406
415
(
2019
).
27.
I.
Islam
,
B. K.
Paul
,
K.
Ahmed
,
R.
Hasan
,
S.
Chowdhury
,
S.
Islam
,
S.
Sen
,
A. N.
Bahar
, and
S.
Asaduzzaman
, “
Highly birefringent single mode spiral shape photonic crystal fiber based sensor for gas sensing applications
,”
Sens. bio-Sens. Res.
14
,
30
38
(
2017
).
28.
A. A. M.
Bulbul
,
R. H.
Jibon
,
M. A.
Awal
,
E.
Podder
,
H. S.
Mondal
,
M. S.
Ahmed
,
M. B.
Hossain
,
M. M.
Hassan
, and
A.
Saha
, “
Toxic chemicals detection using photonic crystal fiber in THz regime
,”
11th International Conference on Computing, Communication and Networking Technologies
(
IEEE ASME Trans.: Mechatron
,
2020
), pp.
1
5
.
29.
W. L. C.
Liao
,
M. L.
Hou
,
L. W.
Chang
,
C. J.
Lee
,
W. M.
Tsai
,
L. C.
Lin
, and
T. H.
Tsai
, “
Determination and pharmacokinetics of di-(2-ethylhexyl) phthalate in rats by ultraperformance liquid chromatography with tandem mass spectrometry
,”
Molecules
18
(
9
),
11452
11466
(
2013
).
30.
M. S.
Islam
,
J.
Sultana
,
A.
Dinovitser
,
K.
Ahmed
,
B. W. H.
Ng
, and
D.
Abbott
, “
Sensing of toxic chemicals using polarized photonic crystal fiber in the terahertz regime
,”
Opt. Commun.
426
,
341
347
(
2018
).
31.
B.
Abdullah Al-Mamun
,
H. M. D.
Bellal
,
D.
Rahul
, and
H.
Mahadi
, “
Zeonex-based tetra-rectangular core-photonic crystal fiber for NaCl detection
,”
Nanosci. Nanotechnol.
10
,
1
9
(
2020
).
32.
F. A.
Mou
,
M. M.
Rahman
,
M. R.
Islam
, and
M. I. H.
Bhuiyan
, “
Development of a photonic crystal fiber for THz wave guidance and environmental pollutants detection
,”
Sens. Biosens. Res.
29
,
100346
(
2020
).
33.
F.
Iqbal
,
S.
Biswas
,
A. A.-M.
Bulbul
,
H.
Rahaman
,
B. M.
Hossain
,
E. M.
Rahaman
, and
A. M.
Awal
, “
Alcohol sensing and classification using PCF-based sensor
,”
Sens. Biosens. Res.
30
,
100384
(
2020
).
34.
A.
Al-Mamun Bulbul
,
H.
Rahaman
,
S.
Biswas
,
M. B.
Hossain
, and
A.-A.
Nahid
, “
Design and numerical analysis of a PCF-based bio-sensor for breast cancer cell detection in the THz regime
,”
Sens. Bio-Sens. Res.
30
,
100388
(
2020
).
35.
R. H.
Jibon
,
E. Md
.
Rahaman
, and
M. A.
Alahe
, “
Detection of primary chemical analytes in the THz regime with photonic crystal fiber
,”
Sens. Bio-Sens. Res.
33
,
100427
(
2021
).
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