The superconducting transition temperatures of C–S–H based on inter-sublattice S−H₄-tetrahedron electronic interactions Available to Purchase

Significant characteristics of the superconducting transitions reported for carbonaceous sulfur hydride [Snider et al., Nature 585, 373 (2020)] are the exceptionally abrupt onset temperatures and their marked increase toward room temperature at high pressures. Theoretical and experimental studies addressing the superconducting composition and structure have thus far returned mixed results. One possibility, consistent with the experimentally suggested stoichiometry of CSH_x, is the theoretically discovered compressed $I4¯3m$ CSH₇ structure [Sun et al., Phys. Rev. B 101, 174102 (2020)], which comprises a sublattice similar to $Im3¯m$ H₃S with CH₄ intercalates. Positing an electronic genesis of the superconductivity, a model is presented in analogy with earlier work on superconductivity in $Im3¯m$ H₃S, in which pairing is induced via purely electronic Coulomb interactions across the mean distance ζ between the S and H₄-tetrahedra enclosing C. Theoretical superconducting transition temperatures for $I4¯3m$ CSH₇ are derived as T_C0 = (2/3)^1/2σ^1/2β/aζ, where β = 1247.4 ŲK is a universal constant, σ is the participating charge fraction, and a is the lattice parameter. Analysis suggests persistent bulk superconductivity with a pressure-dependent σ, increasing from σ = 3.5, determined previously for $Im3¯m$ H₃S, to σ = 7.5 at high pressure owing to additionally participating C–H bond electrons. With a and ζ determined by theoretical structure, T_C0 = 283.6 ± 3.5 K is predicted at 267 ± 10 GPa, in excellent agreement (within uncertainty) with the corresponding experimental T_C = 287.7 ± 1.2 K. Pressure-induced variations in σ combined with experimental uncertainties in pressure yield overall average (T_C− T_C0) = (−0.8 ± 3.5) K.