We studied InAlBiAs thin films of less than 300 nm on the InP substrate with Bi composition up to 3.2%. The samples were grown by molecular beam epitaxy at low growth temperature and were shown to be fully strained to the substrate and have smooth interfaces. A bandgap reduction around 47 meV/%Bi was observed via spectroscopic ellipsometry. The valence band anticrossing model was used to fit the experimental data. The bandgaps of InAlBiAs with more than 3% Bi are much lower than the expected values from the model, which could be the result of alloy disorders.

1.
K.
Alberi
,
J.
Wu
,
W.
Walukiewicz
,
K. M.
Yu
,
O. D.
Dubon
,
S. P.
Watkins
,
C. X.
Wang
,
X.
Liu
,
Y.-J.
Cho
, and
J.
Furdyna
,
Phys. Rev. B
75
,
045203
(
2007
).
2.
S.
Francoeur
,
M.-J.
Seong
,
A.
Mascarenhas
,
S.
Tixier
,
M.
Adamcyk
, and
T.
Tiedje
,
Appl. Phys. Lett.
82
,
3874
(
2003
).
3.
J. P.
Petropoulos
,
Y.
Zhong
, and
J. M. O.
Zide
,
Appl. Phys. Lett.
99
,
031110
(
2011
).
4.
C. A.
Broderick
,
W.
Xiong
,
S. J.
Sweeney
,
E. P.
O’Reilly
, and
J. M.
Rorison
, in 2016 18th International Conference on Transparent Optical Networks (ICTON) (IEEE,
2016
), pp. 1–4.
5.
Y.
Gu
,
Y. G.
Zhang
,
X. Y.
Chen
,
Y. J.
Ma
,
S. P.
Xi
,
B.
Du
, and
H.
Li
,
Appl. Phys. Lett.
108
,
032102
(
2016
).
6.
D. G.
Sellers
,
S. J.
Polly
,
Y.
Zhong
,
S. M.
Hubbard
,
J. M. O.
Zide
, and
M. F.
Doty
,
IEEE J. Photovoltaics
5
,
224
(
2015
).
7.
T.
Thomas
,
A.
Mellor
,
N. P.
Hylton
,
M.
Fhrer
,
D.
Alonso-lvarez
,
A.
Braun
,
N. J.
Ekins-Daukes
,
J. P. R.
David
, and
S. J.
Sweeney
,
Semicond. Sci. Technol.
30
,
094010
(
2015
).
8.
Y.
Zhong
,
P. B.
Dongmo
,
J. P.
Petropoulos
, and
J. M. O.
Zide
,
Appl. Phys. Lett.
100
,
112110
(
2012
).
9.
R. B.
Lewis
,
M.
Masnadi-Shirazi
, and
T.
Tiedje
,
Appl. Phys. Lett.
101
,
082112
(
2012
).
10.
R. D.
Richards
,
F.
Bastiman
,
C. J.
Hunter
,
D. F.
Mendes
,
A. R.
Mohmad
,
J. S.
Roberts
, and
J. P.
David
,
J. Cryst. Growth.
390
,
120
(
2014
).
11.
F.
Bastiman
,
A.
Mohmad
,
J.
Ng
,
J.
David
, and
S.
Sweeney
,
J. Cryst. Growth.
338
,
57
(
2012
).
12.
W.
Bennarndt
,
G.
Boehm
, and
M.-C.
Amann
,
J. Cryst. Growth
436
,
56
(
2016
).
13.
C. M.
Herzinger
and
B. D.
Johs
, “Dielectric function parametric model, and method of use,” Patent No. US5796983A (August 14,
1995
).
14.
P.
Hohenberg
and
W.
Kohn
,
Phys. Rev.
136
,
B864
(
1964
).
15.
W.
Kohn
and
L. J.
Sham
,
Phys. Rev.
140
,
A1133
(
1965
).
16.
J. P.
Perdew
,
A.
Ruzsinszky
,
G. I.
Csonka
,
O. A.
Vydrov
,
G. E.
Scuseria
,
L. A.
Constantin
,
X.
Zhou
, and
K.
Burke
,
Phys. Rev. Lett.
100
,
136406
(
2008
).
17.
J.
Heyd
,
G. E.
Scuseria
, and
M.
Ernzerhof
,
J. Chem. Phys.
118
,
8207
(
2003
).
18.
J.
Heyd
,
G. E.
Scuseria
, and
M.
Ernzerhof
,
J. Chem. Phys.
124
,
219906
(
2006
).
19.
G.
Kresse
and
J.
Hafner
,
Phys. Rev. B
47
,
558
(
1993
).
20.
G.
Kresse
and
J.
Hafner
,
Phys. Rev. B
49
,
14251
(
1994
).
21.
P. E.
Blöchl
,
Phys. Rev. B
50
,
17953
(
1994
).
22.
G.
Kresse
and
D.
Joubert
,
Phys. Rev. B
59
,
1758
(
1999
).
23.
A.
Zunger
,
S.-H.
Wei
,
L.
Ferreira
, and
J. E.
Bernard
,
Phys. Rev. Lett.
65
,
353
(
1990
).
24.
L. C.
Feldman
,
J. W.
Mayer
, and
S. T.
Picraux
,
Materials Analysis by Ion Channeling: Submicron Crystallography
(
Academic Press
,
2012
)
25.
C.
Freysoldt
,
B.
Grabowski
,
T.
Hickel
,
J.
Neugebauer
,
G.
Kresse
,
A.
Janotti
, and
C. G.
Van de Walle
,
Rev. Mod. Phys.
86
,
253
(
2014
).
26.
A.
Wright
and
N.
Modine
,
J. Appl. Phys.
120
,
215705
(
2016
).
27.
G. M. T.
Chai
,
C. A.
Broderick
,
E. P.
O’Reilly
,
Z.
Othaman
,
S. R.
Jin
,
J. P.
Petropoulos
,
Y.
Zhong
,
P. B.
Dongmo
,
J. M. O.
Zide
,
S. J.
Sweeney
, and
T. J. C.
Hosea
,
Semicond. Sci. Technol.
30
,
094015
(
2015
).
28.
E. C. F.
da Silva
, “InxAl1xAs: critical point energies,” in Datasheet from Landolt-Börnstein—Group III Condensed Matter, edited by U. Rössler (Springer-Verlag, Berlin, 2012).
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