Transport properties of CeO0.85F0.15SbS2 and undoped CeOSbS2 under high pressure were investigated experimentally and theoretically. Electrical resistivity measurements of the CeO0.85F0.15SbS2 single crystals were performed under various high pressures using a diamond anvil cell with boron-doped diamond electrodes. The samples showed the insulator to metal transition by applying a high pressure up to 30-40 GPa. On the other hand, the undoped CeOSbS2 showed almost the same transport property with the F-doped sample under high pressure. The valence state analysis using X-ray photoelectron spectroscopy revealed a simple valence state of Ce3+ in CeO0.85F0.15SbS2 and mixed valence state between Ce3+ and Ce4+ in undoped CeOSbS2. The valence fluctuation in Ce carried out the comparable transport nature in both samples. A band calculation suggests that the undoped CeOSbS2 could be metallic under high pressure of 30 GPa in accordance with the experimental results. A superior thermoelectric property of power factor in CeOSbS2 was estimated under high pressure around 20 GPa in comparison with that of ambient pressure.
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21 February 2019
Research Article|
February 15 2019
Pressure-induced insulator to metal transition of mixed valence compound Ce(O,F)SbS2
Ryo Matsumoto;
Ryo Matsumoto
1
National Institute for Materials Science
, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
2
Graduate School of Pure and Applied Sciences, University of Tsukuba
, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan
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Masanori Nagao;
Masanori Nagao
3
Center for Crystal Science and Technology, University of Yamanashi
, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan
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Masayuki Ochi;
Masayuki Ochi
4
Department of Physics, Osaka University, Machikaneyama-cho
, Toyonaka, Osaka 560-0043, Japan
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Hiromi Tanaka;
Hiromi Tanaka
5
National Institute of Technology, Yonago College
, 4448 Hikona, Yonago, Tottori 683-8502, Japan
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Hiroshi Hara;
Hiroshi Hara
1
National Institute for Materials Science
, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
2
Graduate School of Pure and Applied Sciences, University of Tsukuba
, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan
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Shintaro Adachi;
Shintaro Adachi
1
National Institute for Materials Science
, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
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Kazuki Nakamura;
Kazuki Nakamura
5
National Institute of Technology, Yonago College
, 4448 Hikona, Yonago, Tottori 683-8502, Japan
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Ryo Murakami;
Ryo Murakami
5
National Institute of Technology, Yonago College
, 4448 Hikona, Yonago, Tottori 683-8502, Japan
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Sayaka Yamamoto;
Sayaka Yamamoto
5
National Institute of Technology, Yonago College
, 4448 Hikona, Yonago, Tottori 683-8502, Japan
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Tetsuo Irifune;
Tetsuo Irifune
6
Geodynamics Research Center, Ehime University
, Matsuyama, Ehime 790-8577, Japan
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Hiroyuki Takeya;
Hiroyuki Takeya
1
National Institute for Materials Science
, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
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Isao Tanaka;
Isao Tanaka
3
Center for Crystal Science and Technology, University of Yamanashi
, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan
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Kazuhiko Kuroki;
Kazuhiko Kuroki
4
Department of Physics, Osaka University, Machikaneyama-cho
, Toyonaka, Osaka 560-0043, Japan
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Yoshihiko Takano
Yoshihiko Takano
1
National Institute for Materials Science
, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
2
Graduate School of Pure and Applied Sciences, University of Tsukuba
, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan
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J. Appl. Phys. 125, 075102 (2019)
Article history
Received:
November 02 2018
Accepted:
January 21 2019
Citation
Ryo Matsumoto, Masanori Nagao, Masayuki Ochi, Hiromi Tanaka, Hiroshi Hara, Shintaro Adachi, Kazuki Nakamura, Ryo Murakami, Sayaka Yamamoto, Tetsuo Irifune, Hiroyuki Takeya, Isao Tanaka, Kazuhiko Kuroki, Yoshihiko Takano; Pressure-induced insulator to metal transition of mixed valence compound Ce(O,F)SbS2. J. Appl. Phys. 21 February 2019; 125 (7): 075102. https://doi.org/10.1063/1.5079765
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