Activated graphene nanoplatelets (aGNPs) prepared by a hydrothermal method using KOH as activating agent were used as counter electrode for high efficiency dye-sensitized solar cells (DSSCs). After the KOH activation, the scanning electron microscopy image shows that aGNPs demonstrate a more curled, rough, and porous morphology which could contain both micro- and mesopores. The KOH activation changed the stacked layers of GNPs to a more crumpled and curved morphology. The microstructure of large pores significantly increased the electrode surface area and roughness, leading to the high electrocatalytic activity for triiodide reduction at the counter electrode. The DSSCs fabricated using aGNP as counter electrodes were tested under standard AM 1.5 illumination with an intensity of 91.5 mW/cm2. The device achieved an overall power conversion efficiency of 7.7%, which is comparable to the conventional platinum counter electrode (8%). Therefore, the low cost and high performance aGNP based counter electrode is a promising alternative to conventional Pt counter electrode in DSSCs.
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7 April 2016
Research Article|
April 01 2016
Activated graphene nanoplatelets as a counter electrode for dye-sensitized solar cells Available to Purchase
Jiawei Gong;
Jiawei Gong
a)
1Center for Advanced Photovoltaics, Department of Electrical Engineering,
South Dakota State University
, Brookings, South Dakota 57007, USA
2Department of Mechanical Engineering,
North Dakota State University
, Fargo, North Dakota 58102, USA
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Zhengping Zhou;
Zhengping Zhou
a)
1Center for Advanced Photovoltaics, Department of Electrical Engineering,
South Dakota State University
, Brookings, South Dakota 57007, USA
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K. Sumathy;
K. Sumathy
2Department of Mechanical Engineering,
North Dakota State University
, Fargo, North Dakota 58102, USA
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Huojun Yang;
Huojun Yang
3Department of Construction Management and Engineering,
North Dakota State University
, Fargo, North Dakota 58102, USA
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Qiquan Qiao
Qiquan Qiao
b)
1Center for Advanced Photovoltaics, Department of Electrical Engineering,
South Dakota State University
, Brookings, South Dakota 57007, USA
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Jiawei Gong
1,2,a)
Zhengping Zhou
1,a)
K. Sumathy
2
Huojun Yang
3
Qiquan Qiao
1,b)
1Center for Advanced Photovoltaics, Department of Electrical Engineering,
South Dakota State University
, Brookings, South Dakota 57007, USA
2Department of Mechanical Engineering,
North Dakota State University
, Fargo, North Dakota 58102, USA
3Department of Construction Management and Engineering,
North Dakota State University
, Fargo, North Dakota 58102, USA
a)
J. Gong and Z. Zhou contributed equally to this work.
b)
Author to whom correspondence should be addressed. Electronic mail: [email protected].
J. Appl. Phys. 119, 135501 (2016)
Article history
Received:
January 02 2016
Accepted:
March 22 2016
Citation
Jiawei Gong, Zhengping Zhou, K. Sumathy, Huojun Yang, Qiquan Qiao; Activated graphene nanoplatelets as a counter electrode for dye-sensitized solar cells. J. Appl. Phys. 7 April 2016; 119 (13): 135501. https://doi.org/10.1063/1.4945375
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