Activated graphene nanoplatelets (aGNPs) prepared by a hydrothermal method using KOH as activating agent were used as counter electrode for high efficiency dye-sensitized solar cells (DSSCs). After the KOH activation, the scanning electron microscopy image shows that aGNPs demonstrate a more curled, rough, and porous morphology which could contain both micro- and mesopores. The KOH activation changed the stacked layers of GNPs to a more crumpled and curved morphology. The microstructure of large pores significantly increased the electrode surface area and roughness, leading to the high electrocatalytic activity for triiodide reduction at the counter electrode. The DSSCs fabricated using aGNP as counter electrodes were tested under standard AM 1.5 illumination with an intensity of 91.5 mW/cm2. The device achieved an overall power conversion efficiency of 7.7%, which is comparable to the conventional platinum counter electrode (8%). Therefore, the low cost and high performance aGNP based counter electrode is a promising alternative to conventional Pt counter electrode in DSSCs.

1.
B.
O'regan
and
M.
Grätzel
,
Nature
353
,
737
(
1991
).
2.
J.
Gong
,
K.
Sumathy
, and
J.
Liang
,
Int. J. Sustainable Energy
35
,
75
(
2014
).
3.
J.
Gong
,
K.
Sumathy
, and
J.
Liang
,
Renewable Energy
39
,
419
(
2012
).
4.
J.
Gong
,
H.
Qiao
,
S.
Sigdel
,
H.
Elbohy
,
N.
Adhikari
,
Z.
Zhou
,
K.
Sumathy
,
Q.
Wei
, and
Q.
Qiao
,
AIP Adv.
5
,
067134
(
2015
).
5.
J.
Gong
,
J.
Liang
, and
K.
Sumathy
,
Renewable Sustainable Energy Rev.
16
,
5848
(
2012
).
6.
T. N.
Murakami
,
S.
Ito
,
Q.
Wang
,
M. K.
Nazeeruddin
,
T.
Bessho
,
I.
Cesar
,
P.
Liska
,
R.
Humphry-Baker
,
P.
Comte
, and
P.
Péchy
,
J. Electrochem. Soc.
153
,
A2255
(
2006
).
7.
K.
Imoto
,
K.
Takahashi
,
T.
Yamaguchi
,
T.
Komura
,
J.-I.
Nakamura
, and
K.
Murata
,
Sol. Energy Mater. Sol. Cells
79
,
459
(
2003
).
8.
G.
De Filpo
,
F. P.
Nicoletta
,
L.
Ciliberti
,
P.
Formoso
, and
G.
Chidichimo
,
J. Power Sources
274
,
274
(
2015
).
9.
J. D.
Roy-Mayhew
,
D. J.
Bozym
,
C.
Punckt
, and
I. A.
Aksay
,
ACS Nano
4
,
6203
(
2010
).
10.
L.
Kavan
,
J. H.
Yum
, and
M.
Graetzel
,
ACS Appl. Mater. Interfaces
4
,
6999
(
2012
).
11.
L.
Kavan
,
J. H.
Yum
,
M. K.
Nazeeruddin
, and
M.
Gratzel
,
ACS Nano
5
,
9171
(
2011
).
12.
L.
Kavan
,
J.-H.
Yum
, and
M.
Graützel
,
Nano Lett.
11
,
5501
(
2011
).
13.
M.
Kouhnavard
,
N. A.
Ludin
,
B. V.
Ghaffari
,
K.
Sopian
, and
S.
Ikeda
,
ChemSusChem
8
,
1510
(
2015
).
14.
M. J.
Ju
,
I.-Y.
Jeon
,
K.
Lim
,
J. C.
Kim
,
H.-J.
Choi
,
I. T.
Choi
,
Y. K.
Eom
,
Y. J.
Kwon
,
J.
Ko
, and
J.-J.
Lee
,
Energy Environ. Sci.
7
,
1044
(
2014
).
15.
I. Y.
Jeon
,
M. J.
Ju
,
J.
Xu
,
H. J.
Choi
,
J. M.
Seo
,
M. J.
Kim
,
I. T.
Choi
,
H. M.
Kim
,
J. C.
Kim
, and
J. J.
Lee
,
Adv. Funct. Mater.
25
,
1170
(
2015
).
16.
M. J.
Ju
,
I. Y.
Jeon
,
J. C.
Kim
,
K.
Lim
,
H. J.
Choi
,
S. M.
Jung
,
I. T.
Choi
,
Y. K.
Eom
,
Y. J.
Kwon
, and
J.
Ko
,
Adv. Mater.
26
,
3055
(
2014
).
17.
S.
Murali
,
J. R.
Potts
,
S.
Stoller
,
J.
Park
,
M. D.
Stoller
,
L. L.
Zhang
,
Y.
Zhu
, and
R. S.
Ruoff
,
Carbon
50
,
3482
(
2012
).
18.
Y.
Zhu
,
S.
Murali
,
M. D.
Stoller
,
K.
Ganesh
,
W.
Cai
,
P. J.
Ferreira
,
A.
Pirkle
,
R. M.
Wallace
,
K. A.
Cychosz
, and
M.
Thommes
,
Science
332
,
1537
(
2011
).
19.
A.
Ganesan
and
M. M.
Shaijumon
,
Microporous Mesoporous Mater.
220
,
21
(
2016
).
20.
M.
Lillo-Ródenas
,
D.
Cazorla-Amorós
, and
A.
Linares-Solano
,
Carbon
41
,
267
(
2003
).
21.
L.
Sun
,
C.
Tian
,
M.
Li
,
X.
Meng
,
L.
Wang
,
R.
Wang
,
J.
Yin
, and
H.
Fu
,
J. Mater. Chem. A
1
,
6462
(
2013
).
22.
Z.
Wang
,
X.
Zhang
,
X.
Liu
,
M.
Lv
,
K.
Yang
, and
J.
Meng
,
Carbon
49
,
161
(
2011
).
23.
M.
Rashad
,
F.
Pan
,
A.
Tang
,
Y.
Lu
,
M.
Asif
,
S.
Hussain
,
J.
She
,
J.
Gou
, and
J.
Mao
,
J. Magnesium Alloys
1
,
242
(
2013
).
24.
M.
Naebe
,
J.
Wang
,
A.
Amini
,
H.
Khayyam
,
N.
Hameed
,
L. H.
Li
,
Y.
Chen
, and
B.
Fox
,
Sci. Rep.
4
,
4375
(
2014
).
25.
C.
Zhao
,
X.
Chen
,
C.
Zhao
, and
Y.
Liu
,
Energy Fuels
23
,
1766
(
2009
).
26.
E.
Zimmermann
,
P.
Ehrenreich
,
T.
Pfadler
,
J. A.
Dorman
,
J.
Weickert
, and
L.
Schmidt-Mende
,
Nat. Photonics
8
,
669
(
2014
).
27.
H. J.
Snaith
,
Energy Environ. Sci.
5
,
6513
(
2012
).
28.
A. J.
Bard
and
L. R.
Faulkner
,
Electrochemical Methods: Fundamentals and Applications
(
Wiley
,
New York
, 2000), Vol. 2.
29.
M.-Y.
Yen
,
C.-C.
Teng
,
M.-C.
Hsiao
,
P.-I.
Liu
,
W.-P.
Chuang
,
C.-C. M.
Ma
,
C.-K.
Hsieh
,
M.-C.
Tsai
, and
C.-H.
Tsai
,
J. Mater. Chem.
21
,
12880
(
2011
).
30.
G.
Wang
,
W.
Xing
, and
S.
Zhuo
,
J. Power Sources
194
,
568
(
2009
).
31.
A.
Hauch
and
A.
Georg
,
Electrochim. Acta
46
,
3457
(
2001
).
You do not currently have access to this content.