Nickel silicide is considered the best candidate material to achieve the lowest contact resistance in sub 45 nm CMOS devices. NiSi films with thickness 20–60 nm were prepared by rapid thermal annealing of Ni (temperature 230 °C–780 °C) on top of thin 230 nm silicon-on-insulator substrates, with a constant formation ratio. Based on film independent characterizations, a novel model for the interpretation of spectroscopic ellipsometry data, featuring a combination of two Lorentzian oscillators and one Drude dispersion model, is proposed, and its goodness is checked in comparison to other known models. This new approach is proved to deliver more accurate estimation of the film thickness and resistivity.
REFERENCES
1.
E.
Hokelek
and G. Y.
Robinson
, “Aluminum/nickel silicide contacts on silicon
,” Thin Solid Films
53
, 135
(1978
).2.
J. D.
Plummer
, M. D.
Deal
, and P. B.
Griffin
, Silicon VLSI Technology
(Prentice Hall
, 2000
).3.
R.
Doering
and Y.
Nishi
, Handbook of Semiconductor Manufacturing Technology
(CRC Press
, 2007
).4.
L. J.
Chen
, Silicide Technology for Integrated Circuits
(The Institution of Electrical Engineers
, London
, 2004
).5.
S. Y.
Tan
, C. W.
Chen
, I. T.
Chen
, and C. W.
Feng
, “Physical and electrical characterization of Ni–Si phase transformation
,” Thin Solid Films
517
, 1186
(2008
).6.
M.
Van Hove
, Y.
Travaly
, T.
Sajavaara
, B.
Brijs
, W.
Vandervorst
, A.
Lauwers
, O.
Chamirian
, J. A.
Kittl
, A. M.
Jonas
, and K.
Maex
, “Study of thermal stability of nickel silicide by X-ray reflectivity
,” Microelectr. Eng.
82
, 492
(2005
).7.
Y. L.
Jiang
, G. P.
Ru
, X. P.
Qu
, and B. Z.
Li
, “X-ray photoelectron spectroscopy study of NiSi formation on shallow junctions
,” Appl. Surf. Sci.
256
, 698
(2009
).8.
K.
De Keyser
, C.
Van Bocksteal
, R. L.
Van Meirhaeghe
, C.
Detavernier
, E.
Verleysen
, H.
Bender
, W.
Vandervorst
, J.
Jordan-Sweet
, and C.
Lavoie
, “Phase formation and thermal stability of ultrathin nickel-silicides on Si(100)
,” Appl. Phys. Lett.
96
, 173503
(2010
).9.
V. K.
Kamineni
, M.
Raymond
, E. J.
Bersch
, B. B.
Doris
, and A. C.
Diebold
, “Optical metrology of Ni and NiSi thin films used in the self-aligned silicidation process
,” J. Appl. Phys.
107
, 093525
(2010
).10.
A. F.
Mayada
and M.
Shatzkes
, “Grain boundary scattering model
,” Phys. Rev. B
1
, 1382
(1970
).11.
H. G.
Tompkins
and E. A.
Irene
, Handbook of Ellipsometry
(Springer, William Andrew
, Norwich, NY
, 2005
).12.
13.
L. J.
van der Pauw
, “A method of measuring specific resistivity and Hall effect of discs of arbitrary shape
,” Philips Res. Rep.
13
, 1
(1958
).14.
15.
G.
Profeta
, S.
Picozzi
, and A.
Continenza
, “Supersoft silicides: Ab initio study of (001) TSi surfaces and (001) Si/TSi (T=Fe, Co, and Ni) interfaces
,” Phys. Rev. B
70
, 235338
(2004
).16.
P.
Gas
, C.
Girardeaux
, D.
Mangelinck
, and A.
Portavoce
, “Reaction and diffusion at interfaces of micro- and nanostructured materials
,” Mater. Sci. Eng. B
101
, 43
(2003
).17.
L. J.
Chen
, Silicide Technology for Integrated Circuits
(The Institution of Electrical Engineers
, London
, 2004
).18.
J. H.
Gulpen
, A. A.
Kodenstov
, and F. J. J.
van Loo
, “Growth of silicides in Ni-Si and Ni-SiC bulk diffusin couples
,” Z. Metallkd.
86
, 8
(1995
).19.
F.
Nava
, K. N.
Tu
, O.
Thomas
, J. P.
Senateur
, R.
Madar
, A.
Borghesi
, G.
Guizzetti
, U.
Gottlieb
, and O.
Laborde
, “Electrical and optical properties of silicide single crystals and thin films
,” Mater. Sci. Rep.
9
, 141
(1993
).20.
R. M.
Boulet
, A. E.
Dunsworth
, J. -P.
Jan
, and H. L.
Skriver
, “De Haas-van Alphen effect and LMTO bandstructure of NiSi
,” J. Phys. F: Metal Phys.
10
, 2197
–2206
(1980
).21.
O.
Bisi
, C.
Calandra
, U.
del Pennino
, P.
Sassaroli
, and S.
Valeri
, “Correlation effects in valence-band spectra of nickel silicides
,” Phys. Rev. B
30
, 5696
(1984
).22.
M. C.
Cheynet
and R.
Pantel
, “Dielectric and optical properties of nanometric nickel silicides from valence electrons energy-loss spectroscopy experiments
,” Micron
37
, 377
(2006
).23.
O.
Bisi
and C.
Calandra
, “Transition metal silicides: aspects of the chemical bond and trends in the electronic structure
,” J. Phys. C
14
, 5479
(1981
).24.
M.
Amiotti
, A.
Borghesi
, G.
Guizzetti
, and F.
Nava
, “Optical properties of polycrystalline nickel silicides
,” Phys. Rev. B
42
, 8939
(1990
).25.
International Crystal Structure Database
(FIZ Karlsruhe and NIST Ed.
, 2010
) CCode #646089;I.-K.
Suh
, H.
Ohta
, and Y.
Waseda
, J. Mater. Sci.
23
, 757
(1988
).26.
International Crystal Structure Database
(FIZ Karlsruhe and NIST Ed.
, 2010
) CCode #646558;K.
Toman
, Acta Cryst.
4
, 462
(1951
).© 2012 American Institute of Physics.
2012
American Institute of Physics
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