Samples of rice husks were transformed to β (3C)-SiC by microwave processing in controlled conditions of temperature and vacuum. This simple and fast way of producing powdered samples of silicon carbide is technologically important if this material is to be used for electronics, sensors, biotechnology, and other applications. Using x-ray diffraction it was found that the microwave processed sample at 1900 °C consists of β (3C)-SiC phase. Raman scattering measurements confirmed the formation of β (3C)-SiC phase. Transmission electron microscopy revealed the presence of stacking faults along the [111] direction. The presence of 6H/4H stacking faults in 3C phase is explained in terms of their total energies. The presence of these stacking faults with a ∼1 eV band offset between the host 3C and hexagonal stacking faults implies that these stacking faults provide a conduction barrier, and the interfaces between the stacking faults and host lattice act as a heterojunction that may provide potential utility for various optoelectronic applications.
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1 April 2012
Research Article|
April 11 2012
Microwave-induced transformation of rice husks to SiC Available to Purchase
S. B. Qadri;
S. B. Qadri
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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M. A. Imam;
M. A. Imam
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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A. W. Fliflet;
A. W. Fliflet
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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B. B. Rath;
B. B. Rath
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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R. Goswami;
R. Goswami
a)
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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J. D. Caldwell
J. D. Caldwell
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
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S. B. Qadri
M. A. Imam
A. W. Fliflet
B. B. Rath
R. Goswami
a)
J. D. Caldwell
Materials Science and Component Technology Directorate, Naval Research Laboratory
, Washington, DC, USA
a)
Also at SAIC, 1710 SAIC Drive, McLean, Virginia 22102, USA.
J. Appl. Phys. 111, 073523 (2012)
Article history
Received:
February 16 2012
Accepted:
March 07 2012
Citation
S. B. Qadri, M. A. Imam, A. W. Fliflet, B. B. Rath, R. Goswami, J. D. Caldwell; Microwave-induced transformation of rice husks to SiC. J. Appl. Phys. 1 April 2012; 111 (7): 073523. https://doi.org/10.1063/1.3702582
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