Dielectric characteristics of tetragonal tungsten bronze ceramics have been evaluated over a broad temperature and frequency range. A broad dielectric peak with strong frequency dispersion is observed at 140–225 K, which well follows the Vogel–Fulcher relationship and indicates the relaxor ferroelectric nature in the present ceramics. The hysteresis loops varying with temperature are consistent with this dielectric relaxation process and provide the further evidence on the relaxor ferroelectric nature. The nonlinear magnetic hysteresis curve is observed in ceramics at 5 K, indicating the soft magnetic behavior which is related to the tetragonal tungsten bronze crystal structure containing magnetic ions of .
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