We report accurate magnetization measurements on the spin-gap compound NiCl24SC(NH2)2 around the low portion of the magnetic induced phase ordering. The critical density of the magnetization at the phase boundary is analyzed in terms of a Bose–Einstein condensation (BEC) of bosonic particles, and the boson interaction strength is obtained as v0=0.61meV. The detailed analysis of the magnetization data across the transition leads to the conclusion for the preservation of the U(1) symmetry, as required for BEC.

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