La0.9Hf0.1MnO3 (LHMO) films were grown on (001) SrTiO3 (LHMO/STO) and (001) 0.7% Nd-doped STO (LHMO/STON) substrates under the same conditions by using pulsed laser deposition technique. The x-ray diffraction and rocking curve measurements demonstrated high epitaxy and good crystallinity obtained in our films. The curves of resistance versus temperature indicated that the as-grown LHMO film exhibits a paramagnetic-ferromagnetic transition at Curie temperature TC. The LHMO/STON heterojunctions exhibited asymmetric current-voltage characteristics similar to those of traditional semiconductor junctions and a typical temperature-dependent rectifying property in a wide temperature range from 20 to 300 K. The diffusion voltage (Vd) of the junction decreases almost linearly with the decrease in temperature. At a negative bias voltage, the dependence of the junction resistance (V/I) on temperature showed an insulator-metal transition in the vicinity of TC, as the voltage decreased from −2 to −7 V. The results were discussed by considering the band diagram of LHMO/STON junction and the tunneling current through the junction.

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