We report on the structural in-plane anisotropy of GaN films grown on A-plane sapphire substrates by metal organic chemical vapor deposition. It is found that GaN:Si grown on A-face sapphire exhibits a strongly anisotropic wafer bending in the two orthogonal in-plane directions, with a 24% larger curvature along the c-axis of sapphire than along the m-axis. Using a model developed for an elastically anisotropic bilayer structure and using our curvature data, the anisotropic biaxial stresses in the two in-plane directions have been estimated as σ1x1.3GPa and σ1y1.1GPa along parallel and perpendicular to c-axis of sapphire, respectively. This anisotropic stress is also responsible for the distortion of the GaN hexagonal basal plane, as evidenced by x-ray diffraction measurements. The broadening of full width at half maximum of the GaN (0002) x-ray reflections varies with different azimuthal angles, correlated with the tilt of the c-axis of GaN. The in-plane epitaxial relationships between the GaN (0001) and A-face sapphire are found as a-axis of GaN aligned with c-axis of sapphire and m-axis of GaN aligned with m-axis of sapphire.

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