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Spin Transition Materials: Molecular and Solid-State

Bistability and its metastable structure are a principal origin of variety in nature. Spin transition and related materials are a platform of such phenomena, and particularly their well-controlled switchable property has provided seminal applications in information storage, colorimetric sensing, ultra-fast photo-switching, nanoswitches, molecular-spintronics, mechanical-actuation, and more. The aim of this Special Topic is to provide an overview on recent progress of this interesting field and look for further developments. Accepted contributions may include the latest experimental techniques, theoretical and experimental studies of all aspects of spin-crossover materials, such as equilibrium and nonequilibrium properties of macroscopic, nanoparticle and nanostructured systems, and also their applications.

Guest Editors: Kamel Boukheddaden, Seiji Miyashita, and Smail Triki

EDITORIALS

Spin transition materials: Molecular and solid-state

Kamel Boukheddaden; Seiji Miyashita; Smail Triki

https://doi.org/10.1063/5.0135246

TUTORIALS

Tutorial on elastic interaction models for multistep spin-crossover transitions

Masamichi Nishino; Yogendra Singh; Kamel Boukheddaden; Seiji Miyashita

https://doi.org/10.1063/5.0065890

Physics of Materials, Including Electrical, Thermal, Mechanical and Other Properties

High-pressure behavior of heteroepitaxial core–shell particles made of Prussian blue analogs

Isabelle Maurin; Miho Itoi; John M. Cain; Daniel R. Talham; Thierry Gacoin; Kamel Boukheddaden; Jean-Paul Itié

https://doi.org/10.1063/5.0049223

Magnetism, Spintronics, and Superconductivity

Quantum phases of spin-1 system on 3/4 and 3/5 skewed ladders

Sambunath Das; Dayasindhu Dey; S. Ramasesha; Manoranjan Kumar

https://doi.org/10.1063/5.0048811

Magnetism, Spintronics, and Superconductivity

Mn(III) complexes with nitro-substituted ligands—Spin states with a twist

Irina A. Kühne; Laurence C. Gavin; Michelle Harris; Brendan Gildea; Helge Müller-Bunz; Matthias Stein; Grace G. Morgan

https://doi.org/10.1063/5.0050276

TUTORIALS

Spin-crossover materials: Getting the most from x-ray crystallography

Sébastien Pillet

https://doi.org/10.1063/5.0047681

Physics of Materials, Including Electrical, Thermal, Mechanical and Other Properties

Spin-state smectics in spin crossover materials

J. Cruddas; G. Ruzzi; B. J. Powell

https://doi.org/10.1063/5.0045763

Magnetism, Spintronics, and Superconductivity

Microscopic electroelastic modeling of a spin transition with symmetry breaking

Ahmed Slimani; Kamel Boukheddaden

https://doi.org/10.1063/5.0045860

PERSPECTIVES

Stimulus induced strain in spin transition heterostructures

John M. Cain; Wanhong He; Isabelle Maurin; Mark W. Meisel; Daniel R. Talham

https://doi.org/10.1063/5.0045939

Thin Films, Interfaces, and Surfaces

Host–guest exchange contribution to transition temperature downshift in nanocrystalline Fe(pyrazine)[Pt(CN)₄] thin films prepared by matrix-assisted pulsed laser evaporation

Mirosław Sawczak; Rafał Jendrzejewski; Dominik Maskowicz; Yann Garcia; Marinela Dîrtu; Varun Kumar; Gerard Śliwiński

https://doi.org/10.1063/5.0047749

Magnetism, Spintronics, and Superconductivity

Isomorphism between the electro-elastic modeling of the spin transition and Ising-like model with competing interactions: Elastic generation of self-organized spin states

Mamadou Ndiaye; Yogendra Singh; Houcem Fourati; Mouhamadou Sy; Bassirou Lo; Kamel Boukheddaden

https://doi.org/10.1063/5.0045689

Magnetism, Spintronics, and Superconductivity

The ON–OFF switching of thermal spin crossover by interstitial solvent exchange in a layered Re^V–CN–Fe^II coordination framework

Tomasz Charytanowicz; Jakub J. Zakrzewski; Katarzyna Dziedzic-Kocurek; Szymon Chorazy; Barbara Sieklucka

https://doi.org/10.1063/5.0046296

Organic-Inorganic Systems, including Organic Electronics

Coordination isomerism in spin crossover (SCO) materials

Emmelyne Cuza; Rachid Motei; Fatima Setifi; Abdeslem Bentama; Carlos J. Gómez-García; Smail Triki

https://doi.org/10.1063/5.0046055

TUTORIALS

Tutorial on the elastic theory of spin crossover materials

Alexandra-Ioana Popa; Laurentiu Stoleriu; Cristian Enachescu

https://doi.org/10.1063/5.0042788

Magnetism, Spintronics, and Superconductivity

Effects of water removal on the structure and spin-crossover in an anilato-based compound

Samia Benmansour; Patricia Gómez-Claramunt; Carlos J. Gómez-García

https://doi.org/10.1063/5.0045666

Magnetism, Spintronics, and Superconductivity

1D spin-crossover molecular chain with degenerate states

A. Gudyma; Iu. Gudyma

https://doi.org/10.1063/5.0042465

Magnetism, Spintronics, and Superconductivity

Thermal- and photo-induced spin crossover in the 1D coordination polymer [Fe(4-tBupy)₃][Au(CN)₂]₂ (4-tBupy = 4-tert-butylpyridine)

Víctor García-López; Miguel Clemente-León; Eugenio Coronado

https://doi.org/10.1063/5.0046998

Magnetism, Spintronics, and Superconductivity

Modeling of electron transfer phenomenon in the dinuclear {Fe(μ − CN)Co} complexes

Sophia Klokishner; Serghei Ostrovsky

https://doi.org/10.1063/5.0041952

PERSPECTIVES

Photoswitchable high-dimensional Co^II–[W^V(CN)₈] networks: Past, present, and future

Olaf Stefańczyk; Shin-ichi Ohkoshi

https://doi.org/10.1063/5.0042037

Organic-Inorganic Systems, including Organic Electronics

Spin crossover phenomenon in a three-dimensional cyanido-bridged Fe^II–Mo^IV assembly

Shintaro Kawabata; Koji Nakabayashi; Kenta Imoto; Shin-ichi Ohkoshi

https://doi.org/10.1063/5.0041958

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Spin Transition Materials: Molecular and Solid-State

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Spin Transition Materials: Molecular and Solid-State

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