The Belousov–Zhabotinsky (BZ) reaction was investigated to elucidate features of oscillations depending on the applied electrical potential, E. A cation-exchange resin bead loaded with the catalyst of the BZ reaction was placed on a platinum plate as a working electrode and then E was applied. We found that global oscillations (GO) and a reduced state coexisted on the bead at a negative value of E and that the source point of GO changed depending on E. The thickness of the reduced state was determined by a yellow colored region which corresponded to the distribution of Br2. The present studies suggest that the distribution of the inhibitor, Br−, which is produced from Br2, plays an important role in the existence of the reduced state and GO, and the source point of GO.
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July 2022
Research Article|
July 05 2022
Coexistence of oscillatory and reduced states on a spherical field controlled by electrical potential
Yujin Kubodera;
Yujin Kubodera
(Formal analysis, Investigation, Writing – original draft, Writing – review & editing)
1
Graduate School of Integrated Sciences for Life, Hiroshima University
, Kagamiyama 1−3-1, Higashi-Hiroshima 739-8526, Japan
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Mari Horisaka;
Mari Horisaka
(Data curation, Formal analysis, Investigation, Writing – review & editing)
1
Graduate School of Integrated Sciences for Life, Hiroshima University
, Kagamiyama 1−3-1, Higashi-Hiroshima 739-8526, Japan
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Masakazu Kuze
;
Masakazu Kuze
(Data curation, Formal analysis, Writing – review & editing)
2
Organization for the Strategic Coordination of Research and Intellectual Properties, Meiji University
, 4-21-1 Nakano, Nakano-ku, Tokyo 164-8525, Japan
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Nobuhiko J. Suematsu
;
Nobuhiko J. Suematsu
(Methodology, Writing – review & editing)
3
Meiji Institute for Advanced Study of Mathematical Sciences (MIMS) and Graduate School of Advanced Mathematical Sciences, Meiji University
, 4-21-1 Nakano, Nakano-ku, Tokyo 164-8525, Japan
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Takashi Amemiya
;
Takashi Amemiya
(Investigation, Methodology, Writing – review & editing)
4
Graduate School of Environment and Information Sciences, Yokohama National University (YNU)
, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa 240-8501, Japan
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Oliver Steinbock
;
Oliver Steinbock
(Investigation, Methodology, Writing – review & editing)
5
Department of Chemistry and Biochemistry, Florida State University
, Tallahassee, Florida 32306-4390, USA
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Satoshi Nakata
Satoshi Nakata
a)
(Investigation, Project administration, Writing – original draft, Writing – review & editing)
1
Graduate School of Integrated Sciences for Life, Hiroshima University
, Kagamiyama 1−3-1, Higashi-Hiroshima 739-8526, Japan
a)Author to whom correspondence should be addressed: [email protected].
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a)Author to whom correspondence should be addressed: [email protected].
Note: This article is part of the Focus Issue, From Chemical Oscillations to Applications of Nonlinear Dynamics: Dedicated to Richard J. Field on the Occasion of his 80th Birthday.
Chaos 32, 073103 (2022)
Article history
Received:
April 24 2022
Accepted:
June 06 2022
Citation
Yujin Kubodera, Mari Horisaka, Masakazu Kuze, Nobuhiko J. Suematsu, Takashi Amemiya, Oliver Steinbock, Satoshi Nakata; Coexistence of oscillatory and reduced states on a spherical field controlled by electrical potential. Chaos 1 July 2022; 32 (7): 073103. https://doi.org/10.1063/5.0097010
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