Due to an error in the preparation of the manuscript, the solutions of Eqs. (2) and (3), reported in the paper and used in the data fitting, are not correct. We report the correct fitting functions and the revised results of the time resolved data. The error removal leads to a decrease of the Förster radius extracted from the time resolved PL from to , which is closer to the one extracted from the spectra , thus strengthening the general conclusions of the paper. The best fit acceptor decay time is also reduced from about to .
The fitting function for the donor PL is
with .
Good agreement between the best fit curves and the experimental data is still obtained (see Fig. 3) with and fixed to the PDFC best fit values, and with a maximum (see Table I) for sample S5, corresponding to a Förster radius , which is close to the value extracted from the spectra . The solution of Eq. (3), if is
where is the initial donor population. If , the solution is
with . The best fits (see Fig. 4) of the dot relaxation dynamics are obtained by fitting the data to a linear combination of and with relative amplitudes and , in order to take into account of the polymer biexponential decay, with , and and fixed to the donor best fit values.
Relaxation dynamics of the PDFC in all the investigated samples. The dotted lines are the best fit curves. Inset: different contributions to the S5 relaxation.
Relaxation dynamics of the PDFC in all the investigated samples. The dotted lines are the best fit curves. Inset: different contributions to the S5 relaxation.
Doping fraction of the analyzed samples, dot density and best fit Förster factor.
Sample . | Doping fraction dot/molecule . | Dot density . | . |
---|---|---|---|
S1 | |||
S2 | |||
S3 | |||
S4 | |||
S5 |
Sample . | Doping fraction dot/molecule . | Dot density . | . |
---|---|---|---|
S1 | |||
S2 | |||
S3 | |||
S4 | |||
S5 |
Relaxation dynamics of the dot emission in all the investigated samples. The dotted lines are the best fit curves.
Relaxation dynamics of the dot emission in all the investigated samples. The dotted lines are the best fit curves.