Nonreciprocal transport effects can occur in the normal state of conductors and in superconductors when both inversion and time-reversal symmetry are broken. Here, we consider systems where magnetochiral anisotropy of the energy spectrum due to an externally applied magnetic field results in a rectification effect in the normal state and a superconducting (SC) diode effect when the system is proximitized by a superconductor. Focusing on nanowire systems, we obtain analytic expressions for both normal state rectification and SC diode effects that reveal the commonalities—as well as differences—between these two phenomena. Furthermore, we consider the nanowire brought into an (almost) helical state in the normal phase or a topological SC phase when proximitized. In both cases, this reveals that the topology of the system considerably modifies its nonreciprocal transport properties. Our results provide insights into how to determine the origin of nonreciprocal effects and further evince the strong connection of nonreciprocal transport with the topological properties of a system.
A diode is a device in which the resistance depends on the direction of current flow and is a fundamental element of most modern electronics. A diode effect requires a nonreciprocal resistance, R, due to a current, I, such that ; in other words, current is rectified. To achieve such an effect, it is necessary that inversion symmetry and time-reversal symmetry are broken simultaneously. In most cases, time-reversal symmetry is broken by dissipation and inversion symmetry breaking is achieved extrinsically, e.g., a pn-junction.
In contrast, however, it is also possible for a nonreciprocal resistance to arise as an intrinsic property of a material, e.g., due to the band structure. For instance, applying an external magnetic field can result in a magnetochiral anisotropy (MCA) of the band structure that results in a diode effect.1–10 In particular, MCA results in a resistance that is proportional to the current, I, itself, such that , where R0 is the reciprocal resistance, B is the magnetic field strength, and γ the MCA rectification coefficient.4
It has also recently been discovered that it is possible to have a diode effect in superconductors.11–13 In this case, a superconductor exhibits a critical current, , that is dependent on the direction of current flow, such that, e.g., , where ± indicates the direction of current flow.12–42 This effect is known as the superconducting (SC) diode effect, because there exists a range of currents—in the above example —that experiences the zero-resistance of a superconductor in one direction but has a finite resistance for current flow in the opposite direction.12,13
Several mechanisms have been proposed to produce SC diode effects. As in normal state diodes, broken inversion symmetry—either explicitly or intrinsically—and broken time-reversal symmetry—either explicitly by a magnetic field21,22,24 or by some other mechanism17–19,37–40—are required. In particular, it has been shown that MCA of the underlying energy spectrum in a superconductor can also result in a SC diode effect.13,24,25,30
Although normal state rectification and the SC diode effect can both stem from MCA of the energy spectrum,9,24–26 the relationships between the two effects have not been explored. Since MCA rectification can be measured in the normal state, understanding how MCA of the normal state and SC phase relate to each other could provide a pathway to produce hybrid SC diode devices with high efficiencies, which has significant potential technological applications.28,32,35,42,43 Furthermore, such a relationship could provide a measure of the reduction of spin–orbit interaction (SOI) due to metalization effects44,45 in hybrid SC devices.46,47 Finally, it has been shown that SC diode effects can be altered dramatically in the topological SC phase,24,30,48 which is still not fully understood, and further insights into the connections with topology could be gained from the normal state rectification effect.
In this paper, we investigate systems with MCA of the energy spectrum and consider relations between the normal state rectification effect and SC diode effect when proximitized by a superconductor. Focusing on nanowire systems,46,49 we obtain analytic expressions for both normal state rectification and SC diode effects that reveal the links between both phenomena. We also investigate the case where the nanowire is brought into an (almost) helical state in the normal phase or a topological SC phase when proximitized. This reveals that the topology of the system considerably modifies the nonreciprocal transport response. We conclude with a discussion of the relations and differences between these two effects.
First, we investigate normal state nonreciprocal transport in a (quasi) one-dimensional nanowire. In particular, we focus on the diffusive regime with a scattering rate as, e.g., considered in recent experiments on topological insulator nanowires.9 For simplicity, we consider only a single subband of a one-dimensional band structure. As such, we assume that the system is shorter than the localization length and do not take into account other conductivity channels, e.g., in the bulk of the TI nanowire. Although sufficient for our purpose, these contributions can still be important in real experimental systems since they affect γ, the rectification coefficient.
Energy spectrum: schematic normal state band structure, , of a one-dimensional system with spin–orbit interaction (SOI), i.e., a nanowire. Inversion symmetry breaking plays a crucial role in both the case of normal state rectification and the SC diode effect. In particular, a difference in Fermi velocity for the inner and outer branches of the band structure ( ) directly results in an SC diode effect and stems from the difference in band curvature for the inner and outer Fermi points, which results in a normal state rectification. Both the normal state rectification and SC diode effect are substantially modified when a magnetic field component opens a gap at k = 0, as in (b), resulting in an (almost) helical state of the normal state and a topological SC state in the proximitized system.
Energy spectrum: schematic normal state band structure, , of a one-dimensional system with spin–orbit interaction (SOI), i.e., a nanowire. Inversion symmetry breaking plays a crucial role in both the case of normal state rectification and the SC diode effect. In particular, a difference in Fermi velocity for the inner and outer branches of the band structure ( ) directly results in an SC diode effect and stems from the difference in band curvature for the inner and outer Fermi points, which results in a normal state rectification. Both the normal state rectification and SC diode effect are substantially modified when a magnetic field component opens a gap at k = 0, as in (b), resulting in an (almost) helical state of the normal state and a topological SC state in the proximitized system.
The nonreciprocal conductivity can be either reduced or enhanced, depending on the relative ratios of and . However, we assume that the main source of scattering is due to nonmagnetic impurities, and scattering processes that enable spin-flip scattering are small. As a result, backscattering is reduced in the (almost) helical state due to the small scattering matrix element between opposite spin branches. As such, we generically expect that the scattering time will be much longer in the helical state, , and given the fact that it depends on the square of the , there is likely an increase in σ2 in the helical state.
We now turn to the SC diode effect in nanowires.24,33,34,41 We will assume that the superconductivity in the nanowire is induced by the proximity effect, and therefore, no self-consistent treatment of the pairing potential is required. Such a setup was considered numerically in Ref. 24, where it was shown that a change of sign and dramatic reduction in the SC diode efficiency occurred for values of Zeeman energy, Δx, when the topological SC phase transition had occurred. Here, we establish analytically the origin of the SC diode effect and the connection to the topological SC phase transition.
Superconducting diode efficiency: the diode efficiency initially increases linearly with Zeeman energy before saturating at a Zeeman field that is set by the difference in Fermi velocities of the inner and outer branches, see Eq. (15). The linearized approximation utilized for analytic calculations (dark blue line) is a good approximation at low temperatures. For the numerical solution, the full energy spectrum of [see Eq. (7)] is used to find the maxima and minima of the current [see Eq. (10)]. We use hk, as defined in Eq. (1), with and . Here, m0 is the band mass, C the quartic contribution that results in necessary for an SC diode effect, and the linear spin–orbit coefficient. Parameters: Å, .
Superconducting diode efficiency: the diode efficiency initially increases linearly with Zeeman energy before saturating at a Zeeman field that is set by the difference in Fermi velocities of the inner and outer branches, see Eq. (15). The linearized approximation utilized for analytic calculations (dark blue line) is a good approximation at low temperatures. For the numerical solution, the full energy spectrum of [see Eq. (7)] is used to find the maxima and minima of the current [see Eq. (10)]. We use hk, as defined in Eq. (1), with and . Here, m0 is the band mass, C the quartic contribution that results in necessary for an SC diode effect, and the linear spin–orbit coefficient. Parameters: Å, .
Superconducting diode efficiency of the topological phase: numerical calculation of (a) the diode coefficient δ and (b) the ground-state Cooper pair momentum q0 as a function of the Zeeman energy Δx resulting from a magnetic field parallel to the nanowire. Deep within the topological regime ( ), we find that the diode efficiency is considerably suppressed by the presence of a finite pairing momentum q0 in the ground state of the superconductor. We find q0 is not strongly affected by small finite temperature. Normal state Hamiltonian and parameters are the same as Fig. 2. Other than , and .
Superconducting diode efficiency of the topological phase: numerical calculation of (a) the diode coefficient δ and (b) the ground-state Cooper pair momentum q0 as a function of the Zeeman energy Δx resulting from a magnetic field parallel to the nanowire. Deep within the topological regime ( ), we find that the diode efficiency is considerably suppressed by the presence of a finite pairing momentum q0 in the ground state of the superconductor. We find q0 is not strongly affected by small finite temperature. Normal state Hamiltonian and parameters are the same as Fig. 2. Other than , and .
We have investigated the relations between normal state nonreciprocal transport and the SC diode effect in proximitized nanowire systems. In both cases, MCA can result in a difference in the inner and outer Fermi velocities and this is necessary to cause a finite diode effect. This difference in Fermi velocities generically arises either due to cubic SOI or due to a momentum dependent mass term in systems with SOI. We also found that the topology of the system strongly affects its nonreciprocal transport properties for both normal and SC systems. In the (almost) helical normal state, we found that the rectification is generically enhanced due to the expected increase in the scattering time. In contrast, the SC diode effect is substantially reduced due to the emergence of a finite Cooper pair momentum, q0, deep in the topological phase. Our results indicate that systems with large nonreciprocal transport coefficients in the normal state can be prime candidates for SC diodes when proximitized by a superconductor. However, we find that the impact of a magnetic field parallel to the nanowire can be strikingly different for normal state rectification in comparison with the SC diode effect.
SUPPLEMENTARY MATERIAL
See the supplementary material for calculations of the full superconducting energy spectrum, the current density, and details of the numerics used to obtain critical currents
This work was supported by the Georg H. Endress Foundation and the Swiss National Science Foundation. This project received funding from the European Union's Horizon 2020 Research and Innovation Program (ERC Starting Grant, Grant No 757725).
AUTHOR DECLARATIONS
Conflict of Interest
The authors have no conflicts to disclose.
Author Contributions
Georg Angehrn and Henry F. Legg contributed equally to this work.
Georg Angehrn: Formal analysis (equal); Validation (equal); Writing – review & editing (equal). Henry F. Legg: Conceptualization (equal); Supervision (equal); Validation (equal); Writing – original draft (equal); Writing – review & editing (equal). Daniel Loss: Validation (equal); Writing – original draft (equal); Writing – review & editing (equal). Jelena Klinovaja: Conceptualization (equal); Supervision (equal); Validation (equal); Writing – original draft (equal); Writing – review & editing (equal).
DATA AVAILABILITY
The data that support the findings of this study are available within the article and its supplementary material.