Substitution of Sb in FeSb2 by less than 0.5% of Te induces a transition from a correlated semiconductor to an unconventional metal with large effective charge carrier mass m. Spanning the entire range of the semiconductor-metal crossover, we observed an almost constant enhancement of the measured thermopower compared to that estimated by the classical theory of electron diffusion. Using the latter for a quantitative description one has to employ an enhancement factor of 10–30. Our observations point to the importance of electron-electron correlations in the thermal transport of FeSb2, and suggest a route to design thermoelectric materials for cryogenic applications.

1.
G. D.
Mahan
,
Solid State Phys.
51
,
81
(
1997
).
2.
A.
Bentien
,
S.
Johnsen
,
G. K. H.
Madsen
,
B. B.
Iversen
, and
F.
Steglich
,
Europhys. Lett.
80
,
17008
(
2007
).
3.
P.
Sun
,
N.
Oeschler
,
S.
Johnsen
,
B. B.
Iversen
, and
F.
Steglich
,
Phys. Rev. B
79
,
153308
(
2009
).
4.
J. M.
Tomczak
,
K.
Haule
,
T.
Miyake
,
A.
Georges
, and
G.
Kotliar
,
Phys. Rev. B
82
,
085104
(
2010
).
5.
A.
Bentien
,
G. K. H.
Madsen
,
S.
Johnsen
, and
B. B.
Iversen
,
Phys. Rev. B
74
,
205105
(
2006
).
6.
C.
Petrovic
,
Y.
Lee
,
T.
Vogt
,
N. Dj.
Lazarov
,
S. L.
Bud’ko
, and
P. C.
Canfield
,
Phys. Rev. B
72
,
045103
(
2005
).
7.
C.
Petrovic
,
J. W.
Kim
,
S. L.
Bud’ko
,
A. I.
Goldman
,
P. C.
Canfield
,
W.
Choe
, and
G. J.
Miller
,
Phys. Rev. B
67
,
155205
(
2003
).
8.
A. V.
Lukoyanov
,
V. V.
Mazurenko
,
V. I.
Anisimov
,
M.
Sigrist
, and
T. M.
Rice
,
Eur. Phys. J. B
53
,
205
(
2006
).
9.
G.
Mahan
,
B.
Sales
, and
J.
Sharp
,
Phys. Today
50
(
3
),
42
(
1997
).
10.
P.
Sun
,
N.
Oeschler
,
S.
Johnsen
,
B. B.
Iversen
, and
F.
Steglich
,
Appl. Phys. Express
2
,
091102
(
2009
).
11.
P.
Sun
,
N.
Oeschler
,
S.
Johnsen
,
B. B.
Iversen
, and
F.
Steglich
,
Dalton Trans.
39
,
1012
(
2010
).
12.
R.
Hu
,
V. F.
Mitrović
, and
C.
Petrovic
,
Phys. Rev. B
79
,
064510
(
2009
).
13.
T.
Harada
,
J. Phys. Soc. Jpn.
67
,
1352
(
1998
).
14.
K.
Behnia
,
D.
Jaccard
, and
J.
Flouquet
,
J. Phys.: Condens. Matter
16
,
5187
(
2004
).
15.
K. C.
Sood
and
G. S.
Verma
,
Phys. Rev. B
5
,
3165
(
1972
).
16.
κL(=κκe) is estimated based on the Wiedemann–Franz law ρκe/T=L0, with the Lorenz number L0=2.44×108V2/K2.
17.
Y.
Sun
,
S.
Johnsen
,
P.
Eklund
,
M.
Sillassen
,
J.
Bøttiger
,
N.
Oeschler
,
P.
Sun
,
F.
Stgelich
, and
B. B.
Iversen
,
J. Appl. Phys.
106
,
033710
(
2009
).
18.
Y.
Sun
,
E.
Zhang
,
S.
Johnsen
,
M.
Sillassen
,
P.
Sun
,
F.
Steglich
,
J.
Bøttiger
, and
B. B.
Iversen
,
J. Phys. D: Appl. Phys.
43
,
205402
(
2010
).
You do not currently have access to this content.