Measurements of thermal conductivity Λ by time-domain thermoreflectance in the temperature range 100<T<300K are used to characterize the crystalline quality of epitaxial layers of a prototypical oxide, SrTiO3. Twenty samples from five institutions using two growth techniques, molecular beam epitaxy and pulsed laser deposition (PLD), were analyzed. Optimized growth conditions produce layers with Λ comparable to bulk single crystals. Many PLD layers, particularly those that use ceramics as the target material, show surprisingly low Λ. For homoepitaxial layers, the decrease in Λ created by point defects correlates well with the expansion of the lattice parameter in the direction normal to the surface.

1.
M.
Imada
,
A.
Fujimori
, and
Y.
Tokura
,
Rev. Mod. Phys.
70
,
1039
(
1998
).
2.
J. M. D.
Coey
,
M.
Viret
, and
S.
von Molnar
,
Adv. Phys.
48
,
167
(
1999
).
3.
M.
Dawber
,
K. M.
Rabe
, and
J. F.
Scott
,
Rev. Mod. Phys.
77
,
1083
(
2005
).
4.
T.
Ohnishi
,
M.
Lippmaa
,
T.
Yamamoto
,
S.
Meguro
, and
H.
Koinuma
,
Appl. Phys. Lett.
87
,
241919
(
2005
).
5.
N.
Nakagawa
,
H. Y.
Hwang
, and
D. A.
Muller
,
Nature Mater.
5
,
204
(
2006
).
6.
M.
Varela
,
S. D.
Findlay
,
A. R. H. M.
Lupini Christen
,
A. Y.
Borisevich
,
N.
Dellby
,
O. L.
Krivanek
,
P. D.
Nellist
,
M. P.
Oxley
,
L. J.
Allen
, and
S. J.
Pennycook
,
Phys. Rev. Lett.
92
,
095502
(
2004
).
7.
M.
Lippmaa
,
N.
Nakagawa
,
M.
Kawasaki
,
S.
Ohashi
, and
H.
Koinuma
,
Appl. Phys. Lett.
76
,
2439
(
2000
).
8.
S. V.
Kalinin
,
B. J.
Rodriguez
,
A. Y.
Borisevich
,
A. P.
Baddorf
,
N.
Balke
,
H. J.
Chang
,
L. Q.
Chen
,
S.
Choudhury
,
S.
Jesse
,
P.
Maksymovych
,
M. P.
Nikiforov
, and
S. J.
Pennycook
,
Adv. Mater. (Weinheim, Ger.)
22
,
314
(
2010
).
9.
P.
Partyka
,
Y.
Zhong
,
K.
Nordlund
,
R. S.
Averback
,
I. M.
Robinson
, and
P.
Ehrhart
,
Phys. Rev. B
64
,
235207
(
2001
).
10.
J.
Son
,
P.
Moetakef
,
B.
Jalan
,
O.
Bierwagen
,
N. J.
Wright
,
R.
Engel-Herbert
, and
S.
Stemmer
,
Nature Mater.
9
,
482
(
2010
).
11.
M. L.
Scullin
,
C.
Yu
,
M.
Huijben
,
S.
Mukerjee
,
J.
Seidel
,
Q.
Zhan
,
J.
Moore
,
A.
Majumdar
, and
R.
Ramesh
,
Appl. Phys. Lett.
92
,
202113
(
2008
).
12.
G. A.
Slack
,
J. Phys. Chem. Solids
34
,
321
(
1973
).
13.
D. G.
Cahill
and
R. O.
Pohl
,
Annu. Rev. Phys. Chem.
39
,
93
(
1988
).
14.
D. G.
Cahill
,
Rev. Sci. Instrum.
75
,
5119
(
2004
).
15.
Y. K.
Koh
and
D. G.
Cahill
,
Phys. Rev. B
76
,
075207
(
2007
).
16.
K.
Kang
,
Y. K.
Koh
,
C.
Chiritescu
,
X.
Zheng
, and
D. G.
Cahill
,
Rev. Sci. Instrum.
79
,
114901
(
2008
).
17.
See supplementary material at http://dx.doi.org/10.1063/1.3579993 for a full description of the STO samples measured in this work.
18.
B.
Jalan
,
P.
Moetakef
, and
S.
Stemmer
,
Appl. Phys. Lett.
95
,
032906
(
2009
).
19.
C.
Yu
,
M. L.
Scullin
,
M.
Huijben
,
R.
Ramesh
, and
A.
Majumdar
,
Appl. Phys. Lett.
92
,
191911
(
2008
).
20.
C. M.
Brooks
,
L. F.
Kourkoutis
,
T.
Heeg
,
J.
Schubert
,
D. A.
Muller
, and
D. G.
Schlom
,
Appl. Phys. Lett.
94
,
162905
(
2009
).
21.
A. G.
Beattie
and
G. A.
Samara
,
J. Appl. Phys.
42
,
2376
(
1971
).
22.
M.
Roufosse
and
P. G.
Klemens
,
Phys. Rev. B
7
,
5379
(
1973
).
23.
G. A.
Slack
,
Solid State Physics
(
Academic
,
New York City
,
1979
), p.
35
.
24.
H.
Muta
,
K.
Kurosaki
, and
S.
Yamanaka
,
J. Alloys Compd.
392
,
306
(
2005
).
25.
D. G.
Cahill
,
F.
Watanabe
,
A.
Rockett
, and
C. B.
Vining
,
Phys. Rev. B
71
,
235202
(
2005
).
26.
D. A.
Freedman
,
D.
Roundy
, and
T. A.
Arias
,
Phys. Rev. B
80
,
064108
(
2009
).

Supplementary Material

You do not currently have access to this content.