The photostability of the nonlinear optical dye, Hemi-22, improves upon encapsulation in DNA thin films. The interactions of Hemi-22 with DNA, along with the intrinsic properties of DNA are responsible for these remarkable improvements in the photostability of the dye in comparison to the dye in a poly(methyl methacrylate) as a control.

1.
R. E.
Hermes
,
T. H.
Allik
,
S.
Chandra
, and
J. A.
Hutchinson
,
Appl. Phys. Lett.
63
,
877
(
1993
).
2.
P.
Yang
,
G.
Wirnsberger
,
H. C.
Huang
,
S. R.
Cordero
,
M. D.
McGehee
,
B.
Scott
,
T.
Deng
,
G. M.
Whitesides
,
B. F.
Chmelka
,
S. K.
Buratto
, and
G. D.
Stucky
,
Science
287
,
465
(
2000
).
3.
A.
Otomo
,
S.
Yokoyama
,
T.
Nakahama
, and
S.
Mashiko
,
Appl. Phys. Lett.
77
,
3881
(
2000
).
4.
Y.
Kawabe
,
L.
Wang
,
S.
Horinouchi
, and
N.
Ogata
,
Adv. Mater.
12
,
1281
(
2000
).
5.
Y.
Ner
,
J. G.
Grote
,
J. A.
Stuart
, and
G. A.
Sotzing
,
Soft Matter
4
,
1448
(
2008
).
6.
Y.
Ner
,
J. G.
Grote
,
J. A.
Stuart
, and
G. A.
Sotzing
,
Angew. Chem., Int. Ed.
48
,
5134
(
2009
).
7.
Y.
Kawabe
,
L.
Wang
,
T.
Nakamura
, and
N.
Ogata
,
Appl. Phys. Lett.
81
,
1372
(
2002
).
8.
L.
Wang
,
J.
Yoshida
,
N.
Ogata
,
S.
Sasaki
, and
T.
Kajiyama
,
Chem. Mater.
13
,
1273
(
2001
).
9.
K.
Binnemans
,
C.
Bex
,
A.
Venard
,
H.
De Leebeeck
, and
C.
Görller-Walrand
,
J. Mol. Liq.
83
,
283
(
1999
).
10.
N.
Sasaki
,
H.
Ashitaka
,
K.
Ohtomo
, and
A.
Fukui
,
Int. J. Biol. Macromol.
40
,
327
(
2007
).
11.
C. V.
Kumar
,
R. S.
Turner
, and
E. H.
Asuncion
,
J. Photochem. Photobiol., A
74
,
231
(
1993
).
12.
E. B.
Brauns
,
C. J.
Murphy
, and
M. A.
Berg
,
J. Am. Chem. Soc.
120
,
2449
(
1998
).
13.
C. E.
Crespo-Hernández
,
B.
Cohen
, and
B.
Kohler
,
Nature (London)
436
,
1141
(
2005
).
14.
M.
Yamada
,
K.
Kato
,
M.
Nomizu
,
N.
Sakairi
,
K.
Ohkawa
,
H.
Yamamoto
, and
N.
Nishi
,
Chem. Eur. J.
8
,
1407
(
2002
).
15.
See EPAPS supplementary material at http://dx.doi.org/10.1063/1.3262944 for Fig. S1.

Supplementary Material

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