Porous carbon/Co nanocomposites were fabricated by a sol-gel method. The electromagnetic parameters were measured in the 218GHz range. Compared with porous carbon composite, porous carbon/Co nanocomposite has larger dielectric loss due to the enhanced interfacial polarization relaxation loss and Ohmic loss. The maximum reflection loss of the porous C(Co) nanocomposite can reach 40dB at 4.2GHz with 5mm in thickness and the primary microwave absorptive mechanism is ascribed to the dielectric loss. The effect of porous structure on microwave absorption property of the carbon/Co nanocomposite was also discussed.

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