Intermolecular interactions defined by surface free energy of solids are a critical factor affecting adhesion and bonding of the materials. An experimental technique for surface free energy and related properties (wettability and adhesion) modification has been developed and applied to lithium tantalate ferroelectric crystals. The method is based on combination of ultraviolet illumination and low-energy electron irradiation. These two techniques provide controllable wettability tailoring in a wide range of contact angles of 6°–87°. Fabrication of various wetting configurations of contacted and bonded lithium tantalate (LT) pair plates, such as hydrophilic/hydrophilic, hydrophilic/hydrophobic, and hydrophobic/hydrophobic, allows us to demonstrate direct bonding for modified hydrophilic polar LT faces.

1.
M. J.
Missey
,
V.
Dominic
,
L. E.
Myers
, and
R. C.
Eckardt
,
Opt. Lett.
23
,
9
(
1998
).
2.
M.
Alexe
and
U.
Gösele
,
Direct bonding: Application and Technology
(
Springer
,
Berlin
,
2004
).
3.
V. M.
Fridkin
,
Photoferroelectrics
(
Springer
,
Berlin
,
1979
).
4.
A.
Plößl
and
G.
Kräuter
,
Mater. Sci. Eng., R.
25
,
1
(
1999
).
5.
K.
Eda
,
M.
Sugimoto
, and
Y.
Tomita
,
Appl. Phys. Lett.
66
,
12
(
1995
).
6.
M.
Nagakubo
,
S.
Fujino
,
K.
Senda
, and
T.
Hattori
, U.S. Patent No. 5,421,953 (
1995
).
7.
H.
Himi
,
M.
Matsui
,
S.
Fujino
, and
T.
Hattori
,
Jpn. J. Appl. Phys., Part 1
33
,
6
(
1994
).
8.
A. C.
Muir
,
S.
Mailis
, and
R. W.
Eason
,
J. Appl. Phys.
101
,
104916
(
2007
).
9.
G.
Rosenman
,
D.
Aronov
, and
Yu.
Dekhtyar
, PCT Patent Application No. WO 2007/049,280 (
2007
).
10.
D.
Aronov
,
M.
Molotskii
, and
G.
Rosenman
,
Appl. Phys. Lett.
90
,
104104
(
2007
).
11.
M. N.
Devyatkov
,
V. I.
Ktitorov
, and
Y. I.
Samsonov
,
Bull. Acad. Sci. USSR, Phys. Ser. (Engl. Transl.)
40
,
135
(
1976
).
12.
R.
Wang
,
N.
Sakai
,
A.
Fujishima
,
T.
Watanabe
, and
K.
Hashimoto
,
J. Phys. Chem. B
103
,
2188
(
1999
).
13.
R.-D.
Sun
,
A.
Nakajima
,
A.
Fujishima
,
T.
Watanabe
, and
K.
Hashimoto
,
J. Phys. Chem. B
105
,
1984
(
2001
).
14.
A.
Prohorov
and
Yu.
Kuzminov
,
Ferroelectric Crystals for Laser Radiation Control
(
IOP
,
Bristol
,
1990
).
15.
M.
Maeda
,
I.
Suzuki
, and
K.
Sakyama
,
Jpn. J. Appl. Phys., Part 1
31
,
3229
(
1992
).
16.
X.
Feng
,
L.
Feng
,
M.
Jin
,
J.
Zhai
,
L.
Jiang
, and
D.
Zhu
,
J. Am. Chem. Soc.
126
,
62
(
2004
).
17.
J.
Hiller
,
J. Appl. Phys.
15
,
663
(
1944
).
18.
D. K.
Owens
and
R. C.
Wendt
,
J. Appl. Polym. Sci.
13
,
1741
(
1969
).
19.
C. B. E.
Gawith
, Ph.D. thesis,
University of Southampton
,
2001
.
20.
J.
Wilson
and
J. F. B.
Hawkes
,
Optoelectronics
, 2nd ed. (
Prentice Hall
,
UK
,
1989
).
You do not currently have access to this content.