The interaction of hydrogen with InN epitaxial films has been investigated by exposing InN to a remote hydrogen plasma and monitoring changes in the InN optical properties in real time via spectroscopic ellipsometry. Atomic hydrogen reacts swith InN causing nitrogen depletion with formation of indium clusters at the sample surface. After terminating the hydrogenation process, the hydrogen remains stable in the InN host lattice at T<200°C, while at higher temperatures it partially desorbs as NHx and InHx(x=13).

1.
C. G.
Van de Walle
and
J.
Neugebauer
,
J. Appl. Phys.
95
,
3851
(
2004
).
2.
M.
Felici
,
A.
Polimeni
,
G.
Salviati
,
L.
Lazzarini
,
N.
Armani
,
F.
Masia
,
M.
Capizzi
,
F.
Martelli
,
M.
Lazzarino
,
G.
Bais
,
M.
Piccin
,
S.
Rubini
, and
A.
Franciosi
,
Adv. Mater. (Weinheim, Ger.)
18
,
1993
(
2006
).
3.
A.
Polimeni
,
G.
Baldassarri
,
H.
von Högersthal
,
F.
Masia
,
M.
Capizzi
,
A.
Frova
,
S.
Sanna
,
V.
Fiorentini
,
P. J.
Klar
, and
W.
Stolz
,
Phys. Rev. B
69
,
041201R
(
2004
).
4.
E. A.
Davis
,
S. F. J.
Cox
,
R. L.
Lichti
, and
C. G.
Van de Walle
,
Appl. Phys. Lett.
82
,
592
(
2003
).
5.
S.
Limpijumnong
and
C. G.
Van de Walle
,
Phys. Status Solidi B
228
,
303
(
2001
).
6.
J. W.
Lee
,
S. J.
Pearton
,
J. D.
MacKenzie
, and
C. R.
Abernathy
,
Electron. Lett.
31
,
1512
(
1995
).
7.
J.
Wu
,
W.
Walukiewicz
,
W.
Shan
,
K. M.
Yu
,
J. W.
Age
 III
,
S. X.
Li
,
E. E.
Haller
,
H.
Lu
, and
W. J.
Schaff
,
J. Appl. Phys.
94
,
4457
(
2003
).
8.
R. L.
Lichti
,
Y. G.
Celebi
,
S. F. J.
Cox
, and
E. A.
Davis
,
J. Phys.: Condens. Matter
16
,
325
(
2004
).
9.
Y.
Okamoto
,
K.
Takahashi
,
H.
Nakamura
,
Y.
Okada
, and
M.
Kawabe
,
Phys. Status Solidi A
180
,
59
(
2000
).
10.
L. F. J.
Piper
,
T. D.
Veal
,
M.
Walker
,
I.
Mahboob
,
C. F.
McConville
,
H.
Lu
, and
W. J.
Schaff
,
J. Vac. Sci. Technol. A
23
,
617
(
2005
).
11.
M.
Losurdo
,
M.
Giangregorio
,
G.
Bruno
,
T.-H.
Kim
,
P. C.
Wu
,
S.
Choi
,
M.
Morse
,
A.
Brown
,
F.
Masia
,
A.
Polimeni
, and
M.
Capizzi
,
Mater. Res. Soc. Symp. Proc.
892
,
0892
FF08
03
1
(
2006
).
12.
M.
Losurdo
,
M.
Giangregorio
,
G.
Bruno
,
T. H.
Kim
,
P.
Wu
,
S.
Choi
,
A.
Brown
,
F.
Masia
,
M.
Capizzi
, and
A.
Polimeni
,
Appl. Phys. Lett.
90
,
011910
(
2007
).
13.
G.
Bruno
,
M.
Losurdo
, and
P.
Capezzuto
,
Appl. Phys. Lett.
66
,
3573
(
1995
).
14.
M.
Losurdo
,
G.
Bruno
,
T. H.
Kim
,
S.
Choi
, and
A. S.
Brown
,
Appl. Phys. Lett.
88
,
121928
(
2006
).
15.
G.
Bruno
,
P.
Capezzuto
, and
M.
Losurdo
,
Phys. Rev. B
54
,
17175
(
1996
).
16.
J.
Neugebauer
and
C.
Van de Walle
,
Phys. Rev. Lett.
75
,
4452
(
1995
).
17.
S.
Limpijumnong
and
C. G.
Van de Walle
,
Phys. Rev. B
69
,
235203
(
2003
).
18.
F.
Geiger
,
C. A.
Busse
, and
R. I.
Loehrke
,
Int. J. Thermophys.
8
,
425
(
1987
).
19.
Hans-Jörg
Himmel
,
Laurent
Manceron
,
Anthony J.
Downs
, and
Pluton
Pullumbi
,
J. Am. Chem. Soc.
124
,
4448
(
2002
) and reference therein.
20.
R. J.
Baker
,
C.
Jones
,
P. C.
Junk
, and
M.
Kloth
,
Angew. Chem., Int. Ed.
43
,
3852
(
2004
), and references therein.
You do not currently have access to this content.