Using reflectance spectroscopy, the in-plane polarization behavior of unstrained - and -plane GaN films is experimentally investigated. While no in-plane polarization anisotropy is observed for all three band-gap related excitons (, , and ) in unstrained -plane GaN films, the exciton is completely linearly polarized perpendicular to the axis in unstrained -plane GaN films. However, the and excitons are only partially polarized. This observation is in excellent agreement with results based on band-structure calculations using the Bir-Pikus Hamiltonian for the wurtzite crystal structure.
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