Co-doped ZnO nanocluster-assembled films were deposited by nanocluster-beam deposition. Zn0.986Co0.014O nanoclusters remained wurtzite in structure with size of 5nm. Compared with bulk ZnO, a blueshift of 0.28eV was observed in the absorption edge of the film. Two photo-luminescence bands at 378 and 510nm were detected. Room-temperature ferromagnetism was observed in doped ZnO nanocluster-assembled film. Moreover, it exhibited a large saturated magnetization of 1.4μBCo and increased to 3.65μBCo after the film was annealed. The possible mechanisms on the observed ferromagnetism and enhanced magnetic moment were discussed.

2.
J. K.
Furdyna
,
J. Appl. Phys.
64
,
R29
(
1988
).
3.
T.
Dietl
,
H.
Ohno
,
F.
Matsukura
,
J.
Cibert
, and
D.
Ferrand
,
Science
287
,
1019
(
2000
).
4.
K.
Sato
and
H.
Katayama-Yoshida
,
Jpn. J. Appl. Phys., Part 2
39
,
L555
(
2000
).
5.
K.
Samanta
,
P.
Bhattacharya
, and
R. S.
Katiyar
,
Appl. Phys. Lett.
87
,
101903
(
2005
).
6.
W.
Prellier
,
A.
Fouchet
,
B.
Mercey
,
Ch.
Simon
, and
B.
Raveau
,
Appl. Phys. Lett.
82
,
3490
(
2003
).
7.
K.
Rode
,
A.
Anane
,
R.
Mattana
,
J. P.
Contour
,
O.
Durand
, and
R.
LeBourgeois
,
J. Appl. Phys.
93
,
7676
(
2003
).
8.
K. J.
Kim
and
Y. R.
Park
,
Appl. Phys. Lett.
81
,
1420
(
2001
).
9.
S. S.
Yan
,
C.
Ren
,
X.
Wang
,
Y.
Xin
,
Z. X.
Zhou
,
L. M.
Mei
,
M. J.
Ren
,
Y. X.
Chen
, and
Y. H.
Liu
,
Appl. Phys. Lett.
84
,
2376
(
2004
).
10.
A. C.
Tuan
,
J. D.
Bryan
,
A. B.
Pakhomov
,
V.
Shutthanandan
,
S.
Thevuthasan
,
D. E.
McCready
,
D.
Gaspar
,
M. H.
Engelhard
,
J. W.
Rogers
, Jr.
,
K.
Krishnan
,
D. R.
Gamelin
, and
S. A.
Chambers
,
Phys. Rev. B
70
,
054424
(
2004
).
11.
J. B.
Cui
,
Q.
Zeng
, and
U. J.
Gibson
,
J. Appl. Phys.
99
,
08M113
(
2006
).
12.
M.
Abid
,
J. P.
Abid
, and
J. P.
Ansermet
,
J. Electrochem. Soc.
153
,
D138
(
2006
).
13.
Z. W.
Zhao
,
B. K.
Tay
,
J. S.
Chen
,
J. F.
Hu
,
X. W.
Sun
, and
S. T.
Tan
,
Appl. Phys. Lett.
87
,
251912
(
2005
).
14.
Y. R.
Lee
,
A. K.
Ramdas
, and
R. L.
Aggarwal
,
Phys. Rev. B
38
,
10600
(
1988
).
15.
V. A.
Fonoberov
and
A. A.
Balandin
,
Appl. Phys. Lett.
85
,
5971
(
2004
).
16.
K. K.
Kim
,
N.
Koguchi
,
Y. W.
Ok
,
T. Y.
Seong
, and
S. J.
Park
,
Appl. Phys. Lett.
84
,
3810
(
2004
).
17.
Handbook of X-Ray Photoelectron Spectroscopy
(
Physical Electronics
,
Eden Prairie, MN
,
1995
).
18.
G. A.
Garson
,
M. H.
Nassir
, and
M. A.
Langell
,
J. Vac. Sci. Technol. A
14
,
1637
(
1996
).
19.
S. N.
Towle
,
J. R.
Bargar
,
G. E.
Brown
, Jr.
, and
G. A.
Parks
,
J. Colloid Interface Sci.
187
,
62
(
1992
).
20.
J. J.
Chen
,
M. H.
Yu
,
W. L.
Zhou
,
K.
Sun
, and
L. M.
Wang
,
Appl. Phys. Lett.
87
,
173119
(
2005
).
21.
H.
Munekata
,
Adv. Mater. (Weinheim, Ger.)
7
,
82
(
1995
).
22.
S.
Koshihara
,
A.
Oiwa
,
M.
Hirasawa
,
S.
Katsumoto
,
Y.
Iye
,
C.
Urano
,
H.
Takagi
, and
H.
Munekata
,
Phys. Rev. Lett.
78
,
4617
(
1997
).
23.
J. M. D.
Coey
,
M.
Venkatesan
, and
C. B.
Fitzgerald
,
Nat. Mater.
4
,
173
(
2005
).
24.
J. M. D.
Coey
,
A. P.
Douvalis
,
C. B.
Fitzgerald
, and
M.
Venkatesan
,
Appl. Phys. Lett.
84
,
1332
(
2004
).
You do not currently have access to this content.