UV induced negative current produced at low voltages is reported in a photocurrent rectifier device consisting of a sensing region between two nano electrodes placed apart, employing a droplet of enhanced green fluorescent protein as molecular electrolyte. The current-voltage characteristics are discussed in terms of the properties of the thin scale, the position of the Fermi level, the position of the highest occupied molecular orbital-lowest unoccupied molecular orbital gap, and dispersion of states induced by varying dielectric constants.
REFERENCES
1.
2.
H.
Kuhn
and F. T.
Hong
, Molecular Electronics-Biosensors and Biocomputers
(Plenum
, New York
, 1993
).3.
J. R.
Winkler
and H. B.
Gray
, JBIC, J. Biol. Inorg. Chem.
2
, 399
(1997
).4.
J. W.
Choia
and M.
Fujihira
, Appl. Phys. Lett.
84
, 2187
(2004
).5.
Riccardo A.G.
Cinelli
, Vittorio
Pellegrini
, Aldo
Ferrari
, Paolo
Faraci
, Riccardo
Nifosý
, Mudit
Tyagi
, Mauro
Giacca
, and Fabio
Beltram
, Appl. Phys. Lett.
79
, 3353
(2001
).6.
E.
Menéndez-Proupin
and G.
Gutiérrez
, Phys. Rev. B
72
, 035116
(2005
).7.
Z.
Chiragwandi
, O.
Nur
, M.
Willander
, and N.
Calander
, Appl. Phys. Lett.
83
, 5310
(2003
).8.
J. P.
Perdew
, K.
Burke
, and M.
Ernzerhof
, Phys. Rev. Lett.
77
, 3865
(1996
).9.
B. J.
Delley
, Chem. Phys.
92
, 508
(1996
);B. J.
Delley
,J. Phys. Chem.
100
, 6107
(1996
);B. J.
Delley
,Int. J. Quantum Chem.
69
, 423
(1998
);B. J.
Delley
,Chem. Phys.
113
, 7756
(2000
).10.
More details about DMOL3 can be found at http://www.accelrys.com
© 2006 American Institute of Physics.
2006
American Institute of Physics
You do not currently have access to this content.