By a simple process, we manufactured polymer thin-film transistors (PTFTs) using a 2.6 nm thick self-assembled monolayer (SAM) of alkyl chains as the gate dielectric to reduce the operating voltage of the device. These manufactured PTFTs operate with supply voltages of less than 2 V. A densely packed SAM of docosyltrichlorosilanes (DCTS) was a very efficient insulating barrier due to the very limited penetration of polymer transistor molecules into the SAM insulator. The present results show that a DCTS monolayer is suitable for use as a gate dielectric. These results enhance the prospects of using polymer TFTs with a SAM gate dielectric in low-power applications such as identification tags.

1.
H.
Sirringhaus
,
N.
Tessler
, and
R. H.
Friend
,
Science
280
,
1741
(
1998
).
2.
R.
Österbacka
,
C. P.
An
,
X. M.
Jiang
, and
Z. V.
Vardeny
,
Science
287
,
839
(
2000
).
3.
H.
Sirringhaus
,
P. J.
Brown
,
R. H.
Friend
,
M. M.
Nielsen
,
K.
Bechgaard
,
B. M.W.
Langeveld-Voss
,
A. J.H.
Spiering
,
R. A.J.
Janssen
,
E. W.
Meijer
,
P.
Herwig
, and
D. M.
de Leeuw
,
Nature (London)
401
,
685
(
1999
).
4.
N.
Stutzmann
,
R. H.
Friend
, and
H.
Sirringhaus
,
Science
299
,
1881
(
2003
).
5.
C. J.
Drury
,
C. M.J.
Mutsaers
,
C. M.
Hart
,
M.
Matters
, and
D. M.
deLeeuw
,
Appl. Phys. Lett.
73
,
108
(
1998
).
6.
Z.
Bao
,
A.
Dodabalapur
, and
A. J.
Lovinger
,
Appl. Phys. Lett.
69
,
4108
(
1996
).
7.
C. D.
Dimitrakopoulos
and
P. R.L.
Malenfant
,
Adv. Mater. (Weinheim, Ger.)
14
,
99
(
2002
).
8.
G.
Horowitz
,
Adv. Mater. (Weinheim, Ger.)
10
,
365
(
1998
).
9.
D. H.
Kim
,
Y. D.
Park
,
Y.
Jang
,
H. C.
Yang
,
Y. H.
Kim
,
D. G.
Moon
,
S.
Park
,
T.
Chang
,
C.
Chang
,
M.
Joo
,
C. Y.
Ryu
, and
K.
Cho
,
Adv. Funct. Mater.
15
,
77
(
2005
).
10.
D. H.
Kim
,
Y.
Jang
,
Y. D.
Park
, and
K.
Cho
,
Langmuir
21
,
3203
(
2005
).
11.
D. H.
Kim
,
Y. D.
Park
,
Y.
Jang
, and
K.
Cho
,
Macromol. Rapid Commun.
26
,
834
(
2005
).
12.
T. A.
Chen
,
X.
Wu
, and
R. D.
Rieke
,
J. Am. Chem. Soc.
117
,
233
(
1995
).
13.
T. J.
Prosa
,
M. J.
Winokur
, and
R. D.
McCullough
,
Macromolecules
29
,
3654
(
1996
).
15.
Hagen
Klauk
,
Marcus
Halik
,
Ute
Zschieschang
,
Florian
Eder
,
Günter
Schmid
, and
Christine
Dehm
,
Appl. Phys. Lett.
82
,
4175
(
2003
).
16.
J.
Veres
,
S.
Ogier
,
S. W.
Leeming
,
D. C.
Cupertino
, and
S. M.
Khaffaf
,
Adv. Funct. Mater.
13
,
199
(
2003
).
17.
J.
Veres
,
S.
Ogier
,
G.
Lloyd
, and
D.
Leeuw
,
Chem. Mater.
16
,
4543
(
2004
).
18.
P.
Fontaine
,
D.
Goguenheim
,
D.
Deresmes
, and
D.
Vuillaume
,
Appl. Phys. Lett.
62
,
2256
(
1998
).
19.
C.
Boulas
,
J. V.
Davidovits
,
F.
Rondelez
, and
D.
Vuillaume
,
Phys. Rev. Lett.
76
,
4797
(
1996
).
20.
J.
Collet
and
D.
Vuillaume
,
Appl. Phys. Lett.
73
,
2681
(
1998
).
21.
J.
Collet
,
O.
Tharaud
,
A.
Chapoton
, and
D.
Vuillaume
,
Appl. Phys. Lett.
76
,
1941
(
2000
).
22.
S.
Lenfant
,
C.
Krzeminski
,
C.
Delerue
,
G.
Allan
, and
D.
Vuillaume
,
Nano Lett.
3
,
741
(
2003
).
23.
M.
Halik
,
H.
Klauk
,
U.
Zschieschang
,
G.
Schmid
,
C.
Dehm
,
M.
Schütz
,
S.
Maisch
,
F.
Effenberger
,
M.
Brunnbauer
, and
F.
Stellacci
,
Nature (London)
431
,
963
(
2004
).
24.
H.
Sirringhause
,
T.
Kawase
,
R. H.
Friend
,
T.
Shimoda
,
M.
Inbasekaran
,
W.
Wu
, and
E. P.
Woo
,
Science
15
,
2123
(
2000
).
25.
P.
Calvert
,
Chem. Mater.
13
,
3299
(
2001
).
26.
K. E.
Paul
,
W. S.
Wong
,
S. E.
Ready
, and
R. A.
Street
,
Appl. Phys. Lett.
83
,
2070
(
2003
).
27.
D. H.
Lee
,
D.
Kim
,
T.
Oh
, and
K.
Cho
,
Langmuir
20
,
8124
(
2004
).
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