A method for nanoscale patterning of molecularly thin liquids on solid surfaces has been demonstrated. A template surface structure was fabricated by a probe oxidation method and a molecularly thin liquid film was applied to it. The intermolecular interaction between the liquid and solid surfaces is varied by the thickness of the nano-oxide structure and this causes the local variations of the wettability. The method provides liquid patterns with desired shapes on nanometer scale, such as a line with a width of less than 100nm and a nanodroplet with a volume of less than 100zeptoliters.

2.
A. M.
Higgins
and
R. A. L.
Jones
,
Nature (London)
404
,
476
(
2000
).
3.
K.
Kargupta
and
A.
Sharma
,
Phys. Rev. Lett.
86
,
4536
(
2001
).
4.
M.
Gleiche
,
L. F.
Chi
, and
H.
Fuchs
,
Nature (London)
403
,
173
(
2000
).
5.
O. D.
Velev
,
B. G.
Prevo
, and
K. H.
Bhatt
,
Nature (London)
426
,
515
(
2003
).
6.
N.
Abott
,
J. P.
Folkers
, and
G. M.
Whitesides
,
Science
257
,
1380
(
1992
).
7.
C. P.
Lopez
,
H. A.
Biebuyck
,
C. D.
Frisbie
, and
G. M.
Whitesides
,
Science
260
,
647
(
1993
).
8.
H.
Gau
,
S.
Heminguhaus
,
P.
Lenz
, and
R.
Lipowsky
,
Science
283
,
46
(
1999
).
9.
J. A.
Dagata
,
Science
270
,
1625
(
1995
).
10.
E. B.
Cooper
,
S. R.
Manalis
,
H.
Fan
,
H.
Dai
,
K.
Matsumoto
,
S. C.
Minne
,
T.
Hunt
, and
C. F.
Quate
,
Appl. Phys. Lett.
75
,
3566
(
1999
).
11.
K.
Fukuzawa
,
J.
Kawamura
,
T.
Deguchi
,
H.
Zhang
, and
Y.
Mitsuya
,
J. Chem. Phys.
121
,
4358
(
2004
).
12.
S.
Granick
,
Science
253
,
1374
(
1991
).
13.
P. G.
de Gennes
,
Rev. Mod. Phys.
57
,
827
(
1985
).
14.
R.
Seemann
,
S.
Herminghaus
, and
K.
Jacobs
,
Phys. Rev. Lett.
86
,
5534
(
2001
).
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