In this letter we demonstrate a method to tune and optically investigate the two highest-symmetry pseudogaps in artificial opals which occur at the an points of the Brillouin zone and correspond to propagation along the (111) and (100) crystallographic directions, respectively. In particular we show that in artificial opals the gap at the point, which is closed for bare opals, can be opened by controlled infiltration with a high refractive index material such as ZnO. To prove this we take advantage of the fact that, in artificial opals grown by the vertical deposition method, regions with both (100) and (111) orientations of the face centerd cubic lattice occur naturally.
REFERENCES
1.
2.
3.
C.
López
, Adv. Mater. (Weinheim, Ger.)
15
, 1679
(2003
).4.
R.
Mayoral
, J.
Requena
, J. S.
Moya
, C.
López
, A.
Cintas
, H.
Miguez
, F.
Meseguer
, L.
Vázquez
, M.
Holgado
, and A.
Blanco
, Adv. Mater. (Weinheim, Ger.)
9
, 257
(1997
).5.
P.
Jiang
, J. F.
Bertone
, K. S.
Hwang
, and V. L.
Colvin
, Chem. Mater.
11
, 2131
(1999
).6.
H.
Miguez
, E.
Chomski
, F.
García-Santamaría
, M.
Ibisate
, S.
John
, C.
López
, F.
Meseguer
, J. P.
Mondia
, G. A.
Ozin
, O.
Toader
, and H. M.
van Driel
, Adv. Mater. (Weinheim, Ger.)
13
, 1634
(2001
).7.
F.
García-Santamaría
, M.
Ibisate
, I.
Rodríguez
, F.
Meseguer
, and C.
López
, Adv. Mater. (Weinheim, Ger.)
15
, 10
(2003
).8.
K.
Sakoda
, Optical Properties of Photonic Crystals
(Springer
, Berlin, 2001
).9.
I.
Tarhan
and G. H.
Watson
, Phys. Rev. B
54
, 7593
(1996
).10.
E.
Palacios-Lidón
, A.
Blanco
, M.
Ibisate
, F.
Meseguer
, C.
López
, and J.
Sánchez-Dehesa
, Appl. Phys. Lett.
81
, 4925
(2002
).11.
A. Y.
Vlasov
, Xiang-Zheng
Bo
, J. C.
Sturm
, and D. J.
Norris
, Nature (London)
414
, 289
(2001
).12.
Q. B.
Meng
, C. H.
Fu
, Y.
Einaga
, Z. Z.
Gu
, A.
Fujishima
, and O.
Sato
, Chem. Mater.
14
, 83
(2002
).13.
J. W.
Goodwin
, J.
Hearn
, C. C.
Ho
, and R. H.
Ottewill
, Colloid Polym. Sci.
252
, 464
(1974
).14.
B. H.
Juárez
, P. D.
García
, D.
Golmayo
, A.
Blanco
, and C.
López
, Adv. Mater. (Weinheim, Ger.)
(to be published) (early view DOI: 10.1002/adma.200500569).15.
N. D.
Denkov
, O.
Velev
, P.
Kralchevski
, I.
Ivanov
, H.
Yoshimura
, and K.
Nagayama
, Langmuir
8
, 3183
(1992
).16.
P.
Pieranski
, L.
Strzelecki
, and B.
Pansu
, Phys. Rev. Lett.
50
, 900
(1983
).17.
S. G.
Johnson
and J. D.
Joannopoulos
, Opt. Express
8
, 173
(2001
).18.
H.
Miguez
, V.
Kitaev
, and G. A.
Ozin
, Appl. Phys. Lett.
84
, 1239
(2004
).19.
J. F.
Galisteo-López
and C.
López
, Phys. Rev. B
70
, 035108
(2004
).20.
F.
Garcia-Santamaria
, J. F.
Galisteo-López
, P. V.
Braun
, and C.
Lopez
, Phys. Rev. B
71
, 195112
(2005
).21.
A.
Blanco
, H.
Míguez
, F.
Meseguer
, C.
López
, F.
López-Tejeira
, and J.
Sánchez-Dehesa
, Appl. Phys. Lett.
78
, 3181
(2001
).22.
J. F.
Bertone
, P.
Jiang
, K. S.
Hwang
, D. M.
Mittleman
, and V. L.
Colvin
, Phys. Rev. Lett.
83
, 300
(1999
).23.
J. F.
Galisteo-López
, E.
Palacios-Lidón
, E.
Castillo-Martínez
, and C.
López
, Phys. Rev. B
68
, 115109
(2003
).© 2005 American Institute of Physics.
2005
American Institute of Physics
You do not currently have access to this content.