We have evaluated the thermal stability of //Si (001) stacks with atomic force microscopy, x-ray diffraction, transmission electron microscopy, and secondary ion mass spectrometry using a back side polishing approach. Crystallization of the amorphous film was found to occur for rapid thermal anneals (RTA) above 935 °C for 20 s, in flowing . Penetration of Al and La into the underlying Si (001) is clearly observed for RTA at or above 950 °C for 20 s in flowing .
REFERENCES
1.
International Technology Roadmap for Semiconductors (ITRS) 2003
, Front End Processes
(Semiconductor Industry Association
, San Jose, CA, 2003), p. 33
, Fig. 46 (2003
). http://public.itrs.net/.2.
R. M.
Wallace
and G.
Wilk
, Crit. Rev. Solid State Mater. Sci.
28
, 231
(2003
).3.
B.-E.
Park
and H.
Ishiwara
, Appl. Phys. Lett.
79
, 806
(2001
).4.
5.
S.-G.
Lim
, S.
Kriventsov
, T. N.
Jackson
, J. H.
Haeni
, D. G.
Schlom
, A. M.
Balbashov
, R.
Uecker
, P.
Reiche
, J. L.
Freeouf
, and G.
Lucovsky
, J. Appl. Phys.
91
, 4500
(2002
).6.
P. W.
Peacock
and J.
Robertson
, J. Appl. Phys.
92
, 4712
(2002
).7.
L. F.
Edge
, D. G.
Schlom
, S. A.
Chambers
, E.
Cicerrella
, J. L.
Freeouf
, B.
Holländer
, and J.
Schubert
, Appl. Phys. Lett.
84
, 726
(2004
).8.
M.
Quevedo-Lopez
, M.
El-Bouanani
, S.
Addepalli
, J. L.
Duggan
, B. E.
Gnade
, R. M.
Wallace
, M. R.
Visokay
, M.
Douglas
, M. J.
Bevan
, and L.
Colombo
, Appl. Phys. Lett.
79
, 2958
(2001
).9.
10.
S.
Guha
, E. P.
Gusev
, H.
O-Schmidt
, M.
Copel
, L.-Å
Ragnarsson
, N. A.
Bojarczuk
, and P.
Ronsheim
, Appl. Phys. Lett.
81
, 2956
(2002
).11.
The nominal film thicknesses given were calculated from the fluxes of the molecular beams (measured by a quartz crystal microbalance) assuming the amorphous films had the density of crystalline . The areal density of La and Al in the films was confirmed by RBS.
12.
J.
Lettieri
, J. H.
Haeni
, and D. G.
Schlom
, J. Vac. Sci. Technol. A
20
, 1332
(2002
).13.
L. F.
Edge
, D. G.
Schlom
, R. T.
Brewer
, Y. J.
Chabal
, J. R.
Williams
, S. A.
Chambers
, C.
Hinkle
, G.
Lucovsky
, Y.
Yang
, S.
Stemmer
, M.
Copel
, B.
Holländer
, and J.
Schubert
, Appl. Phys. Lett.
84
, 4629
(2004
).14.
Evans Texas, Roundrock, Texas: www.eaglabs.com.
15.
C.
Gu
, R.
Garcia
, A.
Pivovarov
, F.
Stevie
, and D.
Griffis
, Appl. Surf. Sci.
231
, 663
(2004
).16.
L. F.
Edge
, V.
Vaithyanathan
, D. G.
Schlom
, R. T.
Brewer
, Y. J.
Chabal
, Y.
Yang
, S.
Stemmer
, H. S.
Craft
, J.-P.
Maria
, M. E.
Hawley
, B.
Holländer
, J.
Schubert
, and K.
Eisenbeiser
(unpublished).17.
M.
Nieminen
, T.
Sajavaara
, E.
Rauhala
, M.
Putkonen
and L.
Niinistö
, J. Mater. Chem.
11
, 2340
(2001
).18.
V.
Sandu
, J.
Jaklovszky
, D.
Miu
, D.
Drăgulinescu
, C.
Grigoriu
, and M. C.
Bunescu
, J. Mater. Sci. Lett.
13
, 1222
(1994
).19.
M. V.
Cabañas
, C. V.
Ragel
, F.
Conde
, J. M.
González-Calbet
, and M.
Vallet-Regí
, Solid State Ionics
101
, 191
(1997
).20.
T.
Gougousi
, M. J.
Kelly
, D. B.
Terry
, and G. N.
Parsons
, J. Appl. Phys.
93
, 1691
(2003
).21.
H.
Yamada
, T.
Shimizu
, and E.
Suzuki
, Jpn. J. Appl. Phys., Part 2
41
, L368
(2002
).22.
M.
Copel
, E.
Cartier
, and F. M.
Ross
, Appl. Phys. Lett.
78
, 1607
(2001
).23.
T.
Busani
and R. A. B.
Devine
, Fundamentals of Novel Oxide/Semiconductor Interfaces
, edited by C. R. Abernathy, E. Gusev, D. G. Schlom, and S. Stemmer (MRS, Pittsburgh, 2004), Vol. 786, p. E.6.12.124.
L.
Miotti
, K. P.
Bastos
, C.
Driemeier
, I. J.
Baumvol
, M.-C.
Hugon
, and B.
Agius
(unpublished).© 2005 American Institute of Physics.
2005
American Institute of Physics
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