An x-ray diffraction technique is described which, by careful choice of the x-ray reflection used, minimizes errors in composition measurements resulting from strain and uncertainties in the elastic constants of a material. The method is applied to the system, which shows a wide range of values for Poisson’s ratio in the literature and significant variation in strain state due to the high dislocation content and large thermal expansion mismatch with the substrate. It is demonstrated that accurate composition measurements of partially relaxed layers with thickness can be made from a single measurement.
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Note, this is not the same as assuming Vegard’s law for the and lattice parameters since, because the and ratios differ, a deviation from linearity must occur for one of these spacings. The difference between these two assumptions is of order 0.1% in estimated content at 30% .
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2004
American Institute of Physics
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