We have fabricated an efficient organic photovoltaic cell based on a heterojunction of pentacene and C60. Photocurrent action spectra exhibit broad light-harvesting throughout the visible spectrum with a peak external quantum efficiency (EQE) of 58±4% at short-circuit condition. Modeling studies indicate that this high EQE can be partly attributed to the large exciton diffusion length in the pentacene film as well as efficient dissociation of excitons at the pentacene/C60 heterojunction.

1.
P.
Peumans
and
S. R.
Forrest
,
Appl. Phys. Lett.
79
,
126
(
2001
).
2.
J.
Xu
,
S.
Uchida
,
B. P.
Rand
, and
S. R.
Forrest
,
Appl. Phys. Lett.
84
,
3013
(
2004
).
3.
S. E.
Shaheen
,
C. J.
Brabec
,
N. S.
Sariciftci
,
F.
Padinger
,
T.
Fromherz
, and
J. C.
Hummelen
,
Appl. Phys. Lett.
78
,
841
(
2001
).
4.
C.
Waldauf
,
P.
Schilinsky
,
J.
Hauch
, and
C. J.
Brabec
,
Thin Solid Films
451–452
,
503
(
2004
).
5.
C. D.
Dimitrakopoulos
and
P. R. L.
Malenfant
,
Adv. Mater. (Weinheim, Ger.)
14
,
99
(
2002
).
6.
S. F.
Nelson
,
Y.-Y.
Lin
,
D. J.
Gundlach
, and
T. N.
Jackson
,
Appl. Phys. Lett.
72
,
1854
(
1998
).
7.
T. W.
Kelley
,
L. D.
Boardman
,
T. D.
Dunbar
,
D. V.
Muyres
,
M. J.
Pellerite
, and
T. P.
Smith
,
J. Phys. Chem. B
107
,
5877
(
2003
).
8.
O. D.
Jurchescu
,
J.
Baas
, and
T. T. M.
Palstra
,
Appl. Phys. Lett.
84
,
3061
(
2004
).
9.
R.
Signerski
,
G.
Jarosz
, and
J.
Godlewski
,
Synth. Met.
94
,
135
(
1998
).
10.
J.
Puigdollers
,
C.
Voz
,
A.
Orpella
,
I.
Martin
,
M.
Vetter
, and
R.
Alcubilla
,
Thin Solid Films
427
,
367
(
2003
).
11.
J.
Lee
,
S. S.
Kim
,
K.
Kim
,
J. H.
Kim
, and
S.
Im
,
Appl. Phys. Lett.
84
,
1701
(
2004
).
12.
N. J.
Watkins
and
Y.
Gao
,
J. Appl. Phys.
94
,
5782
(
2003
).
13.
P. G.
Schroeder
,
C. B.
France
,
J. B.
Park
, and
B. A.
Parkinson
,
J. Appl. Phys.
91
,
3010
(
2002
).
14.
A. R.
McGhie
,
A. F.
Garito
, and
A. J.
Heeger
,
J. Cryst. Growth
22
,
295
(
1974
).
15.
L. A. A.
Pettersson
,
L. S.
Roman
, and
O.
Inganas
,
J. Appl. Phys.
86
,
487
(
1999
).
16.
P.
Peumans
,
A.
Yakimov
, and
S. R.
Forrest
,
J. Appl. Phys.
93
,
3693
(
2003
).
17.
R. A.
Synowicki
,
Thin Solid Films
313–314
,
394
(
1998
).
18.
S. P.
Park
,
S. S.
Kim
,
J. H.
Kim
,
C. N.
Whang
, and
S.
Im
,
Appl. Phys. Lett.
80
,
2872
(
2002
).
19.
M. J.
Weber
,
Handbook of Optical Materials
(
CRC
, Boca Raton, FL,
2003
), pp.
314
316
.
20.
L. A. A.
Pettersson
,
L. S.
Roman
, and
O.
Inganas
,
J. Appl. Phys.
89
,
5564
(
2001
).
21.

This calculation method requires the linear response of the photocurrent with respect to the light intensity. We confirmed that this cell shows such linearity at least up to JSC=15mAcm2.

22.
C. J.
Brabec
,
A.
Cravino
,
D.
Meissner
,
N. S.
Sariciftci
,
T.
Fromherz
,
M. T.
Rispens
,
L.
Sanchez
, and
J. C.
Hummelen
,
Adv. Funct. Mater.
11
,
374
(
2001
).
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