Epitaxial thin films have been grown by pulsed-laser deposition on Pt(111) bottom electrode epitaxially grown by dc sputtering on sapphire(0001). Four-circle x-ray diffraction reveals the epitaxial growth of the bilayers. The influence of the Pt bottom electrode on the growth of films is discussed in terms of atomic matching at the interface. The remanent polarization is close to with a coercive field of The zero-field relative permittivity is about 132 and the dielectric loss less than to 2%. The decay in remanent polarization is only 16% after switching cycles, confirming the fatigue resistance of the film.
REFERENCES
1.
R.
Ramesh
, S.
Aggarwal
, and O.
Auciello
, Mater. Sci. Eng.
32
, 191
(2001
).2.
C.
A-Paz de Araujo
, J. D.
Cuchlaro
, L. D.
McMillan
, M. C.
Scott
, and J. F.
Scott
, Nature (London)
374
, 627
(1995
).3.
J. F.
Scott
, F. M.
Ross
, C.
A-Paz de Araujo
, M. C.
Scott
, and M.
Huffman
, MRS Bull.
21
, 33
(1996
).4.
5.
J.-J.
Lee
, C.-L.
Thio
, and S.-B.
Desu
, J. Appl. Phys.
78
, 5073
(1995
).6.
R.
Ramesh
, W. K.
Chan
, B.
Wilkens
, H.
Gilchrist
, T.
Sands
, J. M.
Tarascon
, V. G.
Keramidas
, D. K.
Fork
, J.
Lee
, and A.
Safari
, Appl. Phys. Lett.
61
, 1537
(1992
).7.
D. J.
Lichtenwalner
, R.
Dat
, O.
Auciello
, and A. I.
Kingon
, Ferroelectrics
152
, 445
(1994
).8.
9.
10.
11.
D.
Ismunandar
, B. J.
Kennedy
, M.
Gunawan
, and P.
Marsongkohadi
, J. Solid State Chem.
126
, 135
(1996
).12.
S. B.
Desu
, D. P.
Vijay
, X.
Zhang
, and B. P.
He
, Appl. Phys. Lett.
69
, 1719
(1996
).13.
J.-R.
Duclère
, M.
Guilloux-Viry
, C.
Soyer
, E.
Cattan
, A.
Perrin
, and D.
Rémiens
, Appl. Phys. Lett.
81
, 2067
(2002
).14.
15.
G.
Asayama
, J.
Lettieri
, M. A.
Zurburchen
, Y.
Jia
, S.
Trolier-McKinstry
, D. G.
Schlom
, S. K.
Streiffer
, J.-P.
Maria
, S. D.
Bu
, and C. B.
Eom
, Appl. Phys. Lett.
80
, 2371
(2002
).16.
J.-R. Duclère, “Epitaxial growth and characterization of Pulsed Laser Deposited ferroelectric thin films,” Ph.D. thesis, University of Rennes 1, France, 15 October 2002.
17.
J. R.
Duclère
, M.
Guilloux-Viry
, A.
Perrin
, C.
Clerc
, F.
Lalu
, J.
Lesueur
, S. M.
Zanetti
, V.
Bouquet
, and E.
Longo
, Int. J. Inorganic Mater.
3
, 1133
(2001
).18.
J. S.
Lee
, H. H.
Kim
, H. J.
Kwon
, and Y. W.
Jeong
, Appl. Phys. Lett.
73
, 166
(1998
).19.
J.
Lettieri
, M.-A.
Zurbuchen
, Y.
Jia
, D.-G.
Schlom
, S.-K.
Streiffer
, and M.-E.
Hawley
, Appl. Phys. Lett.
76
, 2937
(2000
).20.
H.-N.
Lee
, A.
Visinoiu
, S.
Senz
, C.
Harnagea
, A.
Pignolet
, D.
Hesse
, and U.
Gösele
, J. Appl. Phys.
88
, 6658
(2000
).21.
22.
is orthorhombic with space group Pbnm and lattice constants and at room temperature. The lattice can be considered as a pseudocubic perovskite with
23.
N.
Nukaga
, M.
Mitsuya
, T.
Suzuki
, Y.
Nishi
, M.
Fujimoto
, and H.
Funakubo
, Jpn. J. Appl. Phys.
40
, 5595
(2001
).24.
P.
Yang
, L.
Zheng
, M.
Zhang
, and C.
Lin
, Thin Solid Films
305
, 48
(1997
).25.
Y. P.
Wang
, T.
Zhu
, and Z. G.
Liu
, Appl. Phys. A: Mater. Sci. Process.
74
, 665
(2002
).26.
R. R.
Das
, P.
Bhattacharya
, and R. S.
Katiyar
, Appl. Phys. Lett.
81
, 1672
(2002
).27.
28.
J.
Lettieri
, M. A.
Zurbuchen
, Y.
Jia
, D. G.
Schlom
, S. K.
Streiffer
, M. E.
Hawley
, Appl. Phys. Lett.
77
, 3090
(2000
).29.
S. B.
Xiong
, S.
Migita
, H.
Ota
, and S.
Sakai
, Mater. Lett.
38
, 406
(1999
).30.
This content is only available via PDF.
© 2003 American Institute of Physics.
2003
American Institute of Physics
You do not currently have access to this content.