We report the fabrication of field-effect transistors on single crystals of the highly anisotropic organic semiconductor tetramethyltetraselenafulvalene. We find maximum mobilities of 0.2 cm2/V s at room temperature. We observe an exponential decrease of mobility with decreasing temperature with an activation energy 160±30 meV, independent of sample quality or fabrication method.

1.
T. Ishiguro, K. Yamaji, and G. Saito, Organic Superconductors (Springer, Berlin, 1998).
2.
T. J.
Kistenmacher
,
T. J.
Emge
,
P.
Shu
, and
D. O.
Cowan
,
Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem.
35
,
772
(
1979
).
3.
R. A.
Laudise
,
Ch.
Kloc
,
P. G.
Simpkins
, and
T.
Siegrist
,
J. Cryst. Growth
187
,
449
(
1998
).
4.
F.
Garnier
,
R.
Hajlaoui
,
A.
Yassar
, and
P.
Srivastava
,
Science
265
,
1684
(
1994
).
5.
S. M. Sze, Physics of Semiconductor Devices (Wiley, New York, 1981).
6.
G.
Horowitz
,
Adv. Mater. (Weinheim, Ger.)
10
,
365
(
1998
).
7.
A.
Dodabalapur
,
L.
Torsi
, and
H. E.
Katz
,
Science
268
,
270
(
1995
).
8.
S. F.
Nelson
,
Y.-Y.
Lin
,
D. J.
Gundlach
, and
T. N.
Jackson
,
Appl. Phys. Lett.
72
,
1854
(
1998
).
9.
D.
Emin
,
Phys. Rev. Lett.
25
,
1751
(
1970
).
10.
D.
Emin
,
Phys. Rev. B
4
,
3639
(
1971
).
11.
G.
Horowitz
,
R.
Hajlaoui
,
D.
Fichou
, and
A. E.
Kassmi
,
J. Appl. Phys.
85
,
3202
(
1999
).
12.
A. B.
Chwang
and
C. D.
Frisbie
,
J. Phys. Chem. B
104
,
12202
(
2000
).
13.
F.
Garnier
,
Chem. Phys.
227
,
253
(
1998
).
14.
B.
Xu
,
D.
Fichou
,
G.
Horowitz
, and
F.
Garnier
,
Adv. Mater. (Weinheim, Ger.)
3
,
150
(
1991
).
15.
H. E.
Katz
and
Z.
Bao
,
J. Phys. Chem. B
104
,
671
(
2000
).
16.
E. A. Silinsh, Organic Molecular Crystals (Springer, Berlin, 1980).
17.
T.
Holstein
,
Ann. Phys.
8
,
325
(
1959
).
18.
T.
Holstein
,
Ann. Phys.
8
,
343
(
1959
).
19.
The bandgap of pure TMTSF has never been measured. However, the crystals are clear and violet in color, indicating that the bandgap exceeds 2.5 eV. In addition, there are no reports of the Debye temperature.
This content is only available via PDF.
You do not currently have access to this content.