Low-voltage organic electroluminescence device with an ultrathin, hybrid structure

We have prepared organic light-emitting diodes with a narrow recombination zone confined by an organic double-heterojunction structure using both polymer and small molecules (a hybrid structure). In these light-emitting diodes, we used very thin small molecule layers, down to a total thickness of 40 nm, to achieve an exponential forward characteristic. These layers were evaporated on a highly conductive layer of PEDT:PSS for a high-yield process and for good charge injection at the anode. Although no doping processes were applied during device fabrication, either at the injecting electrodes or in the $Alq3$ layer, the diodes attained high brightness at very low voltage, for instance, 10.000 $cd/m2$ at voltage of 4.7 V.