The relaxor response of the PbxBi4Ti3+xO12+3x(x=2,3) Aurivillius ceramics is reported. The relaxor behavior appears with an increase of the symmetry in the ab plane of the structure and a decrease of the transition temperature. By the application of a bias field on nonpoled samples, it is possible to induce the piezoelectric response. The piezoelectric coefficient in the planar mode of −72 pC/N was measured at 210 °C for Pb2Bi4Ti5O18 ceramic disks. These results represent a step in the search of high-temperature piezoelectric ceramics.

1.
B.
Aurivillius
,
Ark. Kemi
1
,
463
(
1949
).
2.
R. E.
Newnham
,
R. W.
Wolfe
, and
J. F.
Dorrian
,
Mater. Res. Bull.
6
,
1029
(
1971
).
3.
Y.
Masuda
,
H.
Masamoto
,
A.
Baba
,
T.
Goto
, and
T.
Hira
,
Jpn. J. Appl. Phys., Part 1
31
,
3108
(
1992
).
4.
G. A.
Smolenskii
,
V. A.
Isupov
,
A. I.
Agranovskaya
, and
S. N.
Popov
,
Sov. Phys. Solid State
2
,
2584
(
1961
).
5.
G. A.
Smolenskii
,
J. Phys. Soc. Jpn.
28
,
26
(
1970
).
6.
R.
Maalal
,
R.
Von Der Mühll
,
G.
Troillard
, and
J.
Mercurio
,
J. Phys. Chem. Solids
57
,
1957
(
1996
).
7.
F.
Chun
,
D.
Damjanovic
,
O.
Steiner
, and
N.
Setter
,
J. Am. Ceram. Soc.
78
,
3142
(
1995
).
8.
S.
Yi
and
M.
Miyayama
,
J. Ceram. Soc. Jpn.
106
,
296
(
1998
).
9.
J. T. Fielding, Ph.D. thesis, Penn State University, 1993.
10.
B.
Aurivillius
and
P. H.
Fang
,
Phys. Rev.
126
,
893
(
1962
).
11.
T.
Takenaka
and
T.
Sasaki
,
Ferroelectrics
201
,
117
(
1997
).
12.
I. G.
Ismailzade
,
V. I.
Nesterenko
,
F. A.
Mirishli
, and
P. G.
Rustamov
,
Sov. Phys. Crystallogr.
12
,
400
(
1967
).
13.
R. D.
Shannon
,
Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr.
32
,
751
(
1976
).
14.
H.
Shulman
,
D.
Damjanovic
, and
N.
Setter
,
J. Am. Ceram. Soc.
83
,
528
(
2000
).
15.
M.
Villegas
,
A. C.
Caballero
,
C.
Moure
,
P.
Durán
, and
J. F.
Fernández
,
J. Am. Ceram. Soc.
82
,
2411
(
1999
).
16.
M.
Miyayama
and
I. S.
Yi
,
Ceram. Int.
26
,
529
(
2000
).
17.
I. S.
Yi
and
M.
Miyayama
,
J. Ceram. Soc. Jpn.
106
,
296
(
1998
).
18.
R. L.
Whithers
,
J. G.
Thompson
, and
A. D.
Rae
,
J. Solid State Chem.
91
,
404
(
1991
).
19.
B. Jaffe, W. Cook, Jr., and H. Jaffe, Piezoelectric Ceramics (Academic, New York, 1971).
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