The optical properties of a luminescent polymer, poly[1,4-phenylene-1,2-di(phenoxyphenyl) vinylene], have been investigated. Its photoluminescence yield increases unusually in the solid-state over solution, 52%–6% respectively. Investigations into the stimulated emission properties of this material were carried out but no amplified spontaneous emission was observed. To investigate the presence of excited-state absorption features, the photoinduced absorption spectrum was measured. An observed polaron absorption band, from 1.5 to 2.25 eV, overlaps the emission spectra and therefore quenches stimulated emission. This highlights the need to consider the effects of excited-state absorption on the emission when synthesizing new materials.
REFERENCES
1.
R. H.
Friend
, R. W.
Gymer
, A. B.
Holmes
, J. H.
Burroughes
, R. N.
Marks
, C.
Taliani
, D. D. C.
Bradley
, D. A.
Dos Santos
, J. L.
Bredas
, M.
Logdlund
, and W. R.
Salaneck
, Nature (London)
397
, 121
(1999
).2.
F.
Hide
, B. J.
Schwartz
, M. A.
Diaz-Garcia
, and A. J.
Heeger
, Synth. Met.
91
, 35
(1997
).3.
C.
Kallinger
, M.
Hilmer
, A.
Haugeneder
, M.
Perner
, W.
Spirkl
, U.
Lemmer
, J.
Feldmann
, U.
Scherf
, K.
Mullen
, A.
Gombert
, and V.
Wittwer
, Adv. Mater.
10
, 920
(1998
).4.
S. V.
Frolov
, M.
Shkunov
, Z. V.
Vardeny
, and K.
Yoshino
, Phys. Rev. B
56
, R4363
(1997
).5.
N. T.
Harrison
, N.
Tessler
, C. J.
Moss
, K.
Pichler
, and R. H.
Friend
, Opt. Mater.
9
, 178
(1998
).6.
7.
8.
K. P.
Kretsch
, C.
Belton
, S.
Lipson
, W. J.
Blau
, F. Z.
Henari
, H.
Rost
, S.
Pfeiffer
, A.
Teuschel
, H.
Hillman
, and H.-H.
Horhold
, J. Appl. Phys.
86
, 6155
(1999
).9.
10.
G.
Jones II
, W. R.
Jackson
, C.
Choi
, and W. R.
Bergmark
, J. Phys. Chem.
89
, 294
(1985
).11.
12.
J.
Dhote
, K. P.
Kretsch
, A. P.
Davey
, W. J.
Blau
, and H. J.
Byrne
, Synth. Met.
102
, 1529
(1999
).13.
R.
Resel
, B.
Tertinek
, S.
Teasch
, A.
Davey
, W. J.
Blau
, H.-H.
Horhold
, H.
Rost
, and G.
Leising
, Synth. Met.
101
, 96
(1999
).14.
S. M.
Lipson
, D. F.
O’Brien
, H. J.
Byrne
, A. P.
Davey
, and W. J.
Blau
, Thin Solid Films
370
, 262
(2000
).15.
CRC Handbook of Chemistry and Physics, edited by D. R. Lide.
16.
J.
Sturm
, S.
Tasch
, A.
Niko
, G.
Leising
, E.
Toussare
, J.
Zyss
, T. C
Kowalcyk
, K. D.
Singer
, U.
Scherf
, and J.
Huber
, Thin Solid Films
298
, 138
(1997
).17.
18.
C. Reichardt, Solvents and Solvent Effects in Organic Chemistry (VCH, Weinheim, Berlin).
19.
J. Shinar, Handbook of Organic Conductive Molecules and Polymers, edited by H. S. Nalwa, p. 320.
20.
C.
Botta
, C.
Luzzati
, R.
Tubino
, D. D. C.
Bradley
, and R. H.
Friend
, Phys. Rev. B
48
, 14809
(1993
).21.
A. Penzkofer, 2nd annual LUPO Report, EU Esprit Project No. 28580.
22.
P. A.
Lane
, X.
Wei
, and Z. V.
Vardeny
, Phys. Rev. B
56
, 4626
(1997
). (Compare with results displayed in Table II, p. 4636.)
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