Cubic was synthesized from graphite-like at pressures above 18 GPa and temperatures higher than 2200 K. The lattice parameter of at ambient conditions is 3.642(2) Å, which is larger by 1.48% than would be expected based on ideal mixing between diamond and cubic boron nitride. The bulk modulus of is 282 GPa which is one of the highest bulk moduli known for any solid, and is exceeded only by the bulk moduli of diamond and The hardness of is higher than that of single crystals which indicates that the synthesized phase is only slightly less hard than diamond.
REFERENCES
1.
2.
3.
Y.
Kakudate
, M.
Yoshida
, S.
Usuba
, H.
Yokoi
, S.
Fujiwara
, M.
Kawaguchi
, K.
Sako
, and T.
Sawai
, Trans. Mater. Res. Soc. Jpn.
14B
, 1447
(1994
).4.
5.
S. Nakano, in Proceedings of the NIRIM International Symposium on Advanced Materials (NIRIM, Tsukuba, Japan, 1996), pp. 287–292.
6.
H. Kagi, I. Tsuchida, Y. Masuda, M. Okuda, K. Katsura, and M. Wakatsuki, in Proceedings of the Fifteenth AIRAPT International Conference edited by W. A. Trzeciakowski (World Scientific, Singapore, 1996), pp. 258–260.
7.
8.
9.
10.
11.
12.
M.
Thoms
, S.
Bauchau
, D.
Häusermann
, M.
Kunz
, T.
LeBihan
, M.
Mezouar
, and D.
Strawbridge
, Nucl. Instrum. Methods Phys. Res. A
413
, 175
(1998
).13.
A. Hammersley, Program FIT2D (ESRF, Grenoble, France, 1995).
14.
A. C. Larson and R. B. VonDreele, GSAS, General Structure Analysis System (LANL, Los Alamos, New Mexico, 1986).
15.
16.
N. I.
Borimchuk
, W. B.
Zelyavski
, A. V.
Kurdyumov
, and V. V.
Jarosh
, Dokl. Akad. Nauk SSSR
306
, 1381
(1989
).17.
18.
19.
20.
Ph.
Gillet
, G.
Fiquet
, I.
Daniel
, B.
Reynard
, and M.
Hanfland
, Phys. Rev. B
60
, 14660
(1999
).21.
V. L.
Solozhenko
, D.
Häusermann
, M.
Mezouar
, and M.
Kunz
, Appl. Phys. Lett.
72
, 1691
(1998
).22.
23.
C. A. Brooks, in The Properties of Natural and Synthetic Diamond, edited by J. E. Field (Academic, London, 1992), p. 515–546.
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