We have fabricated phosphorescent polymer light-emitting devices with tris(2-phenylpyridine) iridium [Ir(ppy)3] as a triplet emissive dopant in poly(vinylcarbazole) (PVK) host. The device with 8% doping concentration of [Ir(ppy)3] in PVK showed the external quantum efficiency of 1.9% and the peak luminance of 2,500 cd/m2. The emission spectrum of the device exhibited no emission from PVK, indicating that the energy transfer from PVK to [Ir(ppy)3] is efficient. This work demonstrates that efficient electrophosphorescent light-emitting devices can be realized with polymers.

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