We have measured the interband optical absorption of a free-standing sample of Ga0.96In0.04As0.99N0.01 in a wide energy range from 1 to 2.5 eV. We found that the fundamental absorption edge is shifted by 150 meV towards lower energies, and the absorption coefficient measured at higher energies exhibits substantial reduction comparing to that of GaAs. By removing the GaAs substrate, we were able to get an experimental insight into the interband optical transitions and the density of state in this material. The changes can be understood within the band anticrossing model predicting the conduction band splitting. New absorption edges associated with optical transitions from the spin-orbit split off band to the lower conduction subband (1.55 eV) and from the top of the valence band to the upper subband (1.85 eV) are observed.

1.
M.
Weyers
,
M.
Sato
, and
H.
Ando
,
Jpn. J. Appl. Phys., Part 2
31
,
L853
(
1992
).
2.
Su-Huai
Wei
and
A.
Zunger
,
Phys. Rev. Lett.
76
,
664
(
1996
).
3.
A.
Rubio
and
M. L.
Cohen
,
Phys. Rev. B
51
,
4343
(
1995
).
4.
J.
Neugebauer
and
C. G.
Van de Walle
,
Phys. Rev. B
51
,
10568
(
1995
).
5.
W.
Shan
,
W.
Walukiewicz
,
J. W.
Ager
III
,
E. E.
Haller
,
J. F.
Geisz
,
D. J.
Friedman
,
J. M.
Olson
, and
S. R.
Kurz
,
Phys. Rev. Lett.
82
,
1221
(
1999
).
6.
W. Walukiewicz, W. Shan, J. W. Ager III, D. R. Chamberlin, E. E. Hailer, J. F. Geisz, D. J. Friedman, J. M. Olson, and S. R. Kurtz, Proceedings of the 195th Meeting of the Electrochemical Society, Seattle, WA, 1999 (in press).
7.
P.
Perlin
,
S. G.
Subramanya
,
D. E.
Mars
,
J.
Kruger
,
N. A.
Shapiro
,
H.
Siegle
, and
E. R.
Weber
,
Appl. Phys. Lett.
73
,
3703
(
1998
).
8.
J. S.
Blackmore
,
J. Appl. Phys.
53
,
R123
(
1982
).
9.
P. Y. Yu and M. Cardona, Fundamentals of Semiconductors (Springer, Berlin, 1996).
10.
J. D.
Perkins
,
A.
Mascarenhas
,
Y.
Zhang
,
J. F.
Geisz
,
D. J.
Friedman
,
J. M.
Olson
, and
S. R.
Kurtz
,
Phys. Rev. Lett.
82
,
3312
(
1999
).
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