Surface-emitting organic light emitting diode (OLED) was prepared by sputter deposition of indium-tin-oxide on a buffered organic layer structure. Confirming a previous report, a thin film of copper phthalocyanine (CuPc) was found to be a useful buffer layer in preventing sputter damage to the OLED layer structure, particularly the underlying Alq emissive layer. However, the CuPc layer forms an electron-injection barrier with the Alq layer, resulting in increased electron-hole recombination in the nonemissive CuPc layer, and thus a substantial reduction in electroluminescence efficiency. Incorporation of Li at the CuPc/Alq interface was found to reduce the injection barrier at the interface and recover the overall device efficiency with good surface emission characteristics.

1.
C. W.
Tang
and
S. A.
VanSlyke
,
Appl. Phys. Lett.
51
,
913
(
1987
).
2.
G.
Gu
,
V.
Bulovic
,
P. E.
Burrows
,
S. R.
Forrest
, and
M. E.
Thompson
,
Appl. Phys. Lett.
68
,
2606
(
1996
).
3.
G.
Pathasarathy
,
P. E.
Burrows
,
V.
Khalfin
,
V. G.
Kozolov
, and
S. R.
Forrest
,
Appl. Phys. Lett.
72
,
2138
(
1998
).
4.
V.
Bulovic
,
P.
Tian
,
P. E.
Burrows
,
M. R.
Gokhale
,
S. R.
Forrest
, and
M. E.
Thompson
,
Appl. Phys. Lett.
70
,
2954
(
1997
).
5.
S. A.
VanSlyke
,
C. H.
Chen
, and
C. W.
Tang
,
Appl. Phys. Lett.
69
,
2160
(
1996
).
6.
V.
Choong
,
Y.
Park
,
Y.
Gao
,
T.
Wehrmeister
,
K.
Mullen
,
B. R.
Hsieh
, and
C. W.
Tang
,
Appl. Phys. Lett.
69
,
1492
(
1996
).
7.
I. D.
Parker
,
J. Appl. Phys.
75
,
1656
(
1994
).
8.
E. I.
Haskal
,
A.
Curioni
,
P. F.
Seidler
, and
W.
Andreoni
,
Appl. Phys. Lett.
71
,
1151
(
1997
).
9.
J.
Kido
and
T.
Matsumoto
,
Appl. Phys.
73
,
2866
(
1998
).
10.
S. T.
Lee
,
X. Y.
Hou
,
M. G.
Mason
, and
C. W.
Tang
,
Appl. Phys. Lett.
72
,
1593
(
1998
).
11.
A.
Rajagopai
,
C. I.
Wu
, and
A.
Kahn
,
J. Appl. Phys.
83
,
2649
(
1998
).
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