The vibrational modes in Hg1−xCdxTe epitaxial films and HgTe/CdTe superlattices have been investigated by means of far‐infrared (FIR) transmittance spectra at temperatures from 4.2 to 300 K. The observations were put forward in the spectral range from 20 to 350 cm−1, emphasizing the wave‐number region at the low‐frequency side of the reststrahlen absorption band. A series of single‐phonon and two‐phonon modes as well as impurities‐ and defects‐induced vibrational modes are observed. FIR transmission seems to be a good probe for characterization of the perfection of Hg1−xCdxTe films.

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