We present the results of large‐area (20 cm2) diamond deposition from a scaled‐up stagnation‐flow reactor. The reactor uses a unique nozzle geometry that optimizes reagent gas usage. The premixed acetylene–oxygen–hydrogen flames were operated in a highly strained configuration, allowing uniform deposition of diamond with growth rates exceeding 25 μm/h. Substrate temperature control and flame stability of the chemical vapor deposition reactor are described. Diamond films were deposited on a molybdenum substrate with a surface temperature of approximately 1200 K and C/O ratio of 1.03. Diamond film growth results are presented, and film uniformity is assessed using micro‐Raman spectroscopy.

1.
K. F.
McCarty,
E.
Meeks,
R. J.
Kee
, and
A. E.
Lutz,
Appl. Phys. Lett.
63
,
1498
(
1993
).
2.
Y. Hirose and H. Kondo, Extended Abstracts, the 35th Spring Meeting, Japan Applied Physics Society, March 1988, p. 434.
3.
J. A. Cooper and W. A. Yarbrough, Proc. SPIE 1325, 41 (1990).
4.
N. G.
Glumac
and
D. G.
Goodwin,
Thin Solid Films
212
,
122
(
1992
).
5.
J. S.
Kim
and
M. A.
Cappelli,
J. Mater. Res.
10
,
149
(
1995
).
6.
M.
Murayama,
S.
Kojima
, and
K.
Uchida,
J. Appl. Phys.
69
,
7924
(
1991
).
7.
F. C-N.
Hong,
H-M.
Chang,
J-C.
Hsieh,
J-H.
Hwang
, and
J-J.
Wu,
Thin Solid Films
212
,
127
(
1992
).
8.
V. A. Shamamian and J. E. Butler, NRL (private communication).
9.
R. J. Kee, J. A. Miller, G. H. Evans, and G. Dixon-Lewis, Proceedings of the 22nd Symposium (International) on Combustion, Seattle, 1988 (The Combustion Institute, Pittsburgh, 1988), p. 1479.
10.
E. Meeks, R. J. Kee, D. S. Dandy, and M. E. Coltrin, Combust. Flame 92, 144 (1993).
11.
C. F. Edwards and D. W. Hahn, Proceedings of ILASS-95 (Institute for Liquid Atomization and Spray Systems, Troy, MI, 1995), p. 34.
12.
J. J.
Schermer,
J. E. M.
Hogenkamp,
G. C. J.
Otter,
G.
Janssen,
W. J. P.
van Enckevort
, and
L. J.
Giling,
Diam. Relat. Mater.
2
,
1149
(
1993
).
13.
M.
Murakawa,
S.
Takeuchi
, and
Y.
Hirose,
Surf. Coat. Technol.
43/44
,
22
(
1990
).
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