Using a novel ball mill with controlled ball movement, titanium and zirconium nitrides were synthesized by simple milling, at room temperature, of titanium and zirconium elemental powders in molecular nitrogen atmosphere. The structural evolution during milling is studied using x‐ray diffractometry.

1.
A.
Calka
and
A. P.
Radlinski
,
Appl. Phys. Lett.
58
,
119
(
1991
).
2.
A.
Calka
and
A. P.
Radlinski
,
Mater. Sci. Eng. A
134
,
1350
(
1991
).
3.
T. N. Rhodin and G. Erti, The Nature of the Surface Chemical Bond (North-Holland, Amsterdam, 1979).
4.
G. A.
Somorjai
,
Advan. Catal.
21
,
1
(
1977
).
5.
R.
Liu
and
G.
Ehrilich
,
Surface Sci.
119
,
207
(
1982
).
6.
K.
Horn
,
J.
Dinardo
,
W.
Eberhardt
,
H. J.
Freund
, and
E. W.
Plummer
,
Surface Sci.
118
,
465
(
1982
).
7.
L. A.
Manukova
,
Zh. Fiz. Khim.
44
,
177
(
1970
).
8.
B. E.
Nieuwenhuys
,
Surface Sci.
105
,
505
(
1981
).
9.
R. M.
Davies
,
B.
McDermott
, and
C. C.
Koch
,
Met. Trans.
19A
,
2867
(
1988
).
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