We report the successful p‐type doping of CdTe films with arsenic using the photoassisted molecular beam epitaxy growth technique. These doped epilayers were grown at substrate temperatures as low as 180 °C. The room‐temperature hole concentrations in the CdTe:As layers ranged from 7×1015 to 6.2×1018 cm−3 as determined by van der Pauw–Hall effect measurements. We propose a doping mechanism responsible for the high p‐type doping levels observed in the films. The arsenic acceptor ionization energy was found to ∼58–60 meV using low‐temperature photoluminescence measurements.
REFERENCES
1.
K. Zanio, in Semiconductors and Semimetals, edited by R. K. Willardson and A. C. Beer (Academic, New York, 1978), Vol. 13.
2.
R. N.
Bicknell
, N. C.
Giles
, and J. F.
Schetzina
, Appl. Phys. Lett.
49
, 1095
(1986
).3.
R. N.
Bicknell
, N. C.
Giles
, and J. F.
Schetzina
, Appl. Phys. Lett.
49
, 1735
(1986
).4.
S.
Hwang
, R. L.
Harper
, K. A.
Harris
, N. C.
Giles
, R. N.
Bicknell
, J. F.
Schetzina
, D. L.
Dreifus
, R. M.
Kolbas
, and M.
Chu
, J. Vac. Sci. Technol. B
6
, 777
(1988
);or
N. C.
Giles
, R. N.
Bicknell
, R. L.
Harper
, S.
Hwang
, K. A.
Harris
and J. F.
Schetzina
, J. Cryst. Growth
86
, 348
(1988
).5.
R. N.
Bicknell
, N. C.
Giles
, J. F.
Schetzina
, and C.
Hitzman
, J. Vac. Sci. Technol. A
5
, 3059
(1987
).6.
D. L.
Dreifus
, R. M.
Kolbas
, K. A.
Harris
, R. N.
Bicknell
, R. L.
Harper
, and J. F.
Schetzina
, Appl. Phys. Lett.
51
, 931
(1987
).7.
T. H.
Myers
, Yawcheng
Lo
, R. N.
Bicknell
, and J. F.
Schetzina
, Appl. Phys. Lett.
42
, 247
(1983
).8.
T. H.
Myers
, J. F.
Schetzina
, T. J.
Magee
, and R. D.
Ormond
, J. Vac. Sci. Technol. A
1
, 1598
(1983
).9.
10.
J.
Gu
, T.
Kitahara
, K.
Kawakami
, and T.
Sakaguchi
, J. Appl. Phys.
46
, 1184
(1975
).11.
12.
n‐type conductivity in Cd Te films grown under low laser illumination was attributed to shallow residual donor impurities;
S.
Hwang
, R. L.
Harper
, K. A.
Harris
, N. C.
Giles
, R. N.
Bicknell
, J. W.
Cook
, Jr., J. F.
Schetzina
, and M.
Chu
, J. Vac. Sci. Technol. A
6
, 2821
(1988
).13.
E.
Molva
, J. L.
Pautrat
, K.
Saminadayar
, G.
Milchberg
, and N.
Magnea
, Phys. Rev. B
30
, 3344
(1984
).14.
15.
16.
17.
S. K.
Ghandhi
, N. R.
Taskar
, and I. B.
Bhat
, Appl. Phys. Lett.
50
, 900
(1987
).
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