A new technique for measuring thermal emission rates of trapped minority carriers is experimentally demonstrated in reverse‐biased n+p silicon diodes doped with gold, silver, and cobalt. It makes use of a monochromatic light of a proper photon energy to partially fill the traps with minority carriers (electrons). After the light is turned off, the thermal emission rates of the minority carriers are observed. A unique feature is that the thermal emission rates for both the minority and majority carrier traps can be accurately determined in just one p‐n junction, of either a p+n or n+p type.

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