We report the properties of molecular beam epitaxy deposited AlBN thin films on a recently developed epitaxial nitride metal electrode, Nb2N. While a control AlN thin film exhibits standard capacitive behavior, distinct ferroelectric switching is observed in the AlBN films with increasing Boron mole fraction. The measured remnant polarization μC/cm2 and coercive field 1.45 MV/cm in these films are smaller than those recently reported on films deposited by sputtering, due to incomplete wake-up, limited by current leakage. Because AlBN preserves the ultrawide energy bandgap of AlN compared to other nitride hi-K dielectrics and ferroelectrics, and it can be epitaxially integrated with GaN and AlN semiconductors, its development will enable several opportunities for unique electronic, photonic, and memory devices.
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12 August 2024
Research Article|
August 12 2024
Ferroelectric AlBN films by molecular beam epitaxy
Chandrashekhar Savant
;
Chandrashekhar Savant
a)
(Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Resources, Software, Validation, Writing – original draft, Writing – review & editing)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
a)Author to whom correspondence should be addressed: cps259@cornell.edu
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Ved Gund
;
Ved Gund
(Data curation, Formal analysis, Investigation, Methodology, Writing – review & editing)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Kazuki Nomoto
;
Kazuki Nomoto
(Data curation, Investigation, Methodology)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Takuya Maeda
;
Takuya Maeda
(Investigation, Methodology)
3
Kavli Institute at Cornell for Nanoscale Science, Cornell University
, Ithaca, New York 14853, USA
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Shubham Jadhav
;
Shubham Jadhav
(Formal analysis, Investigation)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Joongwon Lee
;
Joongwon Lee
(Formal analysis)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Madhav Ramesh
;
Madhav Ramesh
(Formal analysis)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Eungkyun Kim
;
Eungkyun Kim
(Methodology)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Thai-Son Nguyen
;
Thai-Son Nguyen
(Formal analysis, Methodology)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
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Yu-Hsin Chen
;
Yu-Hsin Chen
(Methodology, Software)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
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Joseph Casamento
;
Joseph Casamento
(Investigation, Project administration, Supervision)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
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Farhan Rana;
Farhan Rana
(Data curation, Investigation, Validation)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Amit Lal;
Amit Lal
(Investigation, Project administration, Resources)
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
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Huili Grace Xing
;
Huili Grace Xing
(Conceptualization, Funding acquisition, Investigation, Project administration, Resources, Supervision)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
3
Kavli Institute at Cornell for Nanoscale Science, Cornell University
, Ithaca, New York 14853, USA
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Debdeep Jena
Debdeep Jena
(Conceptualization, Funding acquisition, Investigation, Methodology, Project administration, Supervision, Writing – original draft, Writing – review & editing)
1
Department of Materials Science and Engineering, Cornell University
, Ithaca, New York 14853, USA
2
School of Electrical and Computer Engineering, Cornell University
, Ithaca, New York 14853, USA
3
Kavli Institute at Cornell for Nanoscale Science, Cornell University
, Ithaca, New York 14853, USA
4
School of Applied and Engineering Physics, Cornell University
, Ithaca, New York 14853, USA
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a)Author to whom correspondence should be addressed: cps259@cornell.edu
Appl. Phys. Lett. 125, 072902 (2024)
Article history
Received:
October 15 2023
Accepted:
July 01 2024
Citation
Chandrashekhar Savant, Ved Gund, Kazuki Nomoto, Takuya Maeda, Shubham Jadhav, Joongwon Lee, Madhav Ramesh, Eungkyun Kim, Thai-Son Nguyen, Yu-Hsin Chen, Joseph Casamento, Farhan Rana, Amit Lal, Huili Grace Xing, Debdeep Jena; Ferroelectric AlBN films by molecular beam epitaxy. Appl. Phys. Lett. 12 August 2024; 125 (7): 072902. https://doi.org/10.1063/5.0181217
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