Continuous miniaturization of electronic components puts higher demands on the heat dissipation of the micro-systems, which requires environmental friendliness, good heat exchange capability, and high-performance micro-refrigeration materials. Here, we developed a Ni–Mn–Fe–In microwire fabricated by the Taylor–Ulitovsky method, showing ⟨001⟩A orientation close to the axial direction of microwire. Due to the large volume change ΔV/V (−1.24%), the large entropy change ΔStr of 43.6 J kg−1 K−1 was achieved in the microwire. Owing to the low driving force of the microwire with a single crystalline of ⟨001⟩A orientation close to the axial direction of microwire, large adiabatic temperature change of −5.7 K was achieved at room temperature after removing a low stress of 120 MPa. Thus, high specific adiabatic temperature change of 47.5 K/GPa was obtained in the microwire, which is the highest value among all the reported low-dimension elastocaloric materials, including thin films/foils, microwires/wires, and ribbons. The outstanding comprehensive properties give this microwire a great application potential in miniaturization and compactness of refrigeration devices.
REFERENCES
1.
M.
Imran
and
X.
Zhang
, Mater. Des.
195
, 109030
(2020
).2.
J.
Chen
,
L.
Lei
, and
G.
Fang
, Mater. Today Commun.
28
, 102706
(2021
).3.
J.
Tušek
,
K.
Engelbrecht
,
R.
Millan-Solsona
,
L.
Mañosa
,
E.
Vives
,
L.
Mikkelsen
, and
N.
Pryds
, Adv. Eng. Mater.
5
(13
), 1500361
(2015
).4.
T.
Krenke
,
E.
Duman
,
M.
Acet
,
E. F.
Wassermann
,
X.
Moya
,
L.
Mañosa
, and
A.
Planes
, Nat. Mater.
4
(6
), 450
(2005
).5.
L.
Mañosa
,
D.
Gonzalez-Alonso
,
A.
Planes
,
E.
Bonnot
,
M.
Barrio
,
J. L.
Tamarit
,
S.
Aksoy
, and
M.
Acet
, Nat. Mater.
9
(6
), 478
(2010
).6.
Y.
Liu
,
J. F.
Scott
, and
B.
Dkhil
, Appl. Phys. Rev.
3
(3
), 031102
(2016
).7.
R. Z. W.
Goetzler
,
J.
Young
, and
C.
Johnson
, Rep. U.S. Dept. Energy
OSTI Technical Report (2014
).8.
D. Y.
Cong
,
W. X.
Xiong
,
A.
Planes
,
Y.
Ren
,
L.
Mañosa
,
P. Y.
Cao
,
Z. H.
Nie
,
X. M.
Sun
,
Z.
Yang
,
X. F.
Hong
, and
Y. D.
Wang
, Phys. Rev. Lett.
122
(25
), 255703
(2019
).9.
H.
Ossmer
,
F.
Lambrecht
,
M.
Gültig
,
C.
Chluba
,
E.
Quandt
, and
M.
Kohl
, Acta Mater.
81
, 9
(2014
).10.
Y.
Cheng
and
C.-H.
Chen
, J. Alloys Compd.
968
, 171990
(2023
).11.
Z.
Yang
,
D.
Cong
,
Y.
Yuan
,
R.
Li
,
H.
Zheng
,
X.
Sun
,
Z.
Nie
,
Y.
Ren
, and
Y.
Wang
, Appl. Mater. Today
21
, 100844
(2020
).12.
B.
Yuan
,
X.
Zhu
,
X.
Zhang
, and
M.
Qian
, J. Mater. Sci.
54
(13
), 9613
(2019
).13.
L.
Manosa
,
S.
Jarque-Farnos
,
E.
Vives
, and
A.
Planes
, Appl. Phys. Lett.
103
, 211904
(2013
).14.
N.-H.
Lu
and
C.-H.
Chen
, Mater. Sci. Eng. A
800
, 140386
(2021
).15.
X.
Zhang
,
N.
Xu
,
J.
Yang
,
Y.
Niu
,
Y.
Cao
,
D.
Cong
,
H.
Chen
, and
Y.-D.
Wang
, Mater. Lett.
362
, 136165
(2024
).16.
Y.
Niu
,
H.
Chen
,
X.
Zhang
,
S.
Li
,
D.
Cong
,
T.
Ma
,
S.
Li
,
J.
Lin
, and
Y.-D.
Wang
, Scr. Mater.
204
, 114123
(2021
).17.
E.
Villa
,
F.
Villa
,
B. R.
Crespo
,
P.
Lazpita
,
D.
Salazar
,
H.
Hosoda
, and
V.
Chernenko
, J. Alloys Compd.
965
, 171437
(2023
).18.
Z.
Li
,
Z.
Li
,
D.
Li
,
J.
Yang
, and
L.
Zuo
, Appl. Phys. Lett.
115
(8
), 083903
(2019
).19.
J.
Yang
,
H.
Wang
,
Z.
Li
,
N.
Zou
,
H.
Yan
,
B.
Yang
, and
L.
Zuo
, Acta Mater.
263
, 119546
(2024
).20.
M.
Imran
and
X.
Zhang
, Mater. Des.
206
, 109784
(2021
).21.
C.
Bechtold
,
C.
Chluba
,
R.
Lima de Miranda
, and
E.
Quandt
, Appl. Phys. Lett.
101
(9
), 091903
(2012
).22.
S. Y.
Fedotov
,
E. V.
Morozov
,
V. V.
Koledov
,
V. G.
Shavrov
, and
A. V.
Shelyakov
, Bull. Russ. Acad. Sci. Phys.
81
(11
), 1374
(2017
).23.
X.
Zhang
,
M.
Qian
,
X.
Zhu
,
C.
Shang
, and
L.
Geng
, APL Mater.
6
(3
), 036102
(2018
).24.
X.
Zhu
,
X.
Zhang
, and
M.
Qian
, AIP Adv.
8
(12
), 125002
(2018
).25.
J.
Cui
,
Y.
Wu
,
J.
Muehlbauer
,
Y.
Hwang
,
R.
Radermacher
,
S.
Fackler
,
M.
Wuttig
, and
I.
Takeuchi
, Appl. Phys. Lett.
101
(7
), 073904
(2012
).26.
B.
Yuan
,
S.
Zhong
,
M.
Qian
,
X.
Zhang
, and
L.
Geng
, J. Alloys Compd.
850
, 156612
(2021
).27.
B.
Yuan
,
M.
Qian
,
X.
Zhang
, and
L.
Geng
, Scr. Mater.
178
, 356
(2020
).28.
F.
Bruederlin
,
L.
Bumke
,
C.
Chluba
,
H.
Ossmer
,
E.
Quandt
, and
M.
Kohl
, Energy Technol.
6
(8
), 1588
(2018
).29.
F.
Bruederlin
,
H.
Ossmer
,
F.
Wendler
,
S.
Miyazaki
, and
M.
Kohl
, J. Phys. D: Appl. Phys.
50
(42
), 424003
(2017
).30.
L.
Bumke
,
C.
Zamponi
,
J.
Jetter
, and
E.
Quandt
, J. Appl. Phys.
127
(22
), 225105
(2020
).31.
J.
Liu
,
T. G.
Woodcock
,
N.
Scheerbaum
, and
O.
Gutfleisch
, Acta Mater.
57
(16
), 4911
(2009
).32.
H.
Chiriac
and
T. A.
Óvári
, Prog. Mater. Sci.
40
(5
), 333
(1996
).33.
H.
Wang
,
D.
Li
,
G.
Zhang
,
Z.
Li
,
B.
Yang
,
H.
Yan
,
D.
Cong
,
C.
Esling
,
X.
Zhao
, and
L.
Zuo
, Intermetallics
140
, 107379
(2022
).34.
J.
Fornell
,
N.
Tuncer
, and
C. A.
Schuh
, J. Alloys Compd.
693
, 1205
(2017
).35.
Z.
Chen
,
D.
Cong
,
X.
Sun
,
Y.
Zhang
,
H.
Yan
,
S.
Li
,
R.
Li
,
Z.
Nie
,
Y.
Ren
, and
Y.
Wang
, IUCrJ
6
(5
), 843
(2019
).36.
H.
Chen
,
Y.-D.
Wang
,
Z.
Nie
,
R.
Li
,
D.
Cong
,
W.
Liu
,
F.
Ye
,
Y.
Liu
,
P.
Cao
,
F.
Tian
,
X.
Shen
,
R.
Yu
,
L.
Vitos
,
M.
Zhang
,
S.
Li
,
X.
Zhang
,
H.
Zheng
,
J. F.
Mitchell
, and
Y.
Ren
, Nat. Mater.
19
(7
), 712
(2020
).37.
Z.
Chen
,
Y.
Zhang
,
L.
Wang
,
D.
Cong
, and
X.
Sun
, Appl. Phys. Lett.
125
(2
), 023102
(2024
).38.
M.
Vázquez
,
H.
Chiriac
,
A.
Zhukov
,
L.
Panina
, and
T.
Uchiyama
, Phys. Status Solidi A
208
(3
), 493
(2011
).39.
E.
Stern-Taulats
,
A.
Planes
,
P.
Lloveras
,
M.
Barrio
,
J.-L.
Tamarit
,
S.
Pramanick
,
S.
Majumdar
,
S.
Yüce
,
B.
Emre
,
C.
Frontera
, and
L.
Mañosa
, Acta Mater.
96
, 324
(2015
).40.
C. O.
Aguilar-Ortiz
,
D.
Soto-Parra
,
P.
Álvarez-Alonso
,
P.
Lázpita
,
D.
Salazar
,
P. O.
Castillo-Villa
,
H.
Flores-Zúñiga
, and
V. A.
Chernenko
, Acta Mater.
107
, 9
(2016
).41.
V.
Recarte
,
M.
Zbiri
,
M.
Jiménez-Ruiz
,
V.
Sánchez-Alarcos
, and
J. I.
Pérez-Landazábal
, J. Phys. Condens. Mater.
28
(20
), 205402
(2016
).42.
B.
Yuan
,
M.
Qian
,
X.
Zhang
,
M.
Imran
, and
L.
Geng
, Int. J. Refrig.
114
, 54
(2020
).43.
X.
Zhu
,
M.
Qian
,
X.
Zhang
,
S.
Zhong
,
Z.
Jia
,
R.
Zhang
,
A.
Li
, and
L.
Geng
, J. Alloys Compd.
956
, 170291
(2023
).44.
J.
Tušek
,
K.
Engelbrecht
,
L. P.
Mikkelsen
, and
N.
Pryds
, J. Appl. Phys.
117
(12
), 124901
(2015
).45.
X.
Liang
,
F.
Xiao
,
M.
Jin
,
X.
Jin
,
T.
Fukuda
, and
T.
Kakeshita
, Scr. Mater.
134
, 42
(2017
).46.
F.
Xiao
,
Z.
Li
,
H.
Chen
,
Z.
Li
,
K.
Huang
,
X.
Jin
, and
T.
Fukuda
, Materialia
9
, 100547
(2020
).47.
C.
Chluba
,
W.
Ge
,
R. L.
de Miranda
,
J.
Strobel
,
L.
Kienle
,
E.
Quandt
, and
M.
Wuttig
, Science
348
(6238
), 1004
(2015
).48.
H.
Ossmer
,
C.
Chluba
,
M.
Gueltig
,
E.
Quandt
, and
M.
Kohl
, Shap. Mem. Superelasticity
1
, 142
(2015
).49.
H.
Ossmer
,
S.
Miyazaki
, and
M.
Kohl
, Mater. Today Proc.
2
, S971
(2015
).50.
C.
Chluba
,
H.
Ossmer
,
C.
Zamponi
,
M.
Kohl
, and
E.
Quandt
, Shap. Mem. Superelasticity
2
, 95
(2016
).51.
L.
Bumke
,
C.
Chluba
,
H.
Ossmer
,
C.
Zamponi
,
M.
Kohl
, and
E.
Quandt
, Phys. Status Solidi B
255
(2
), 1700299
(2018
).52.
G.
Ulpiani
,
F.
Bruederlin
,
R.
Weidemann
,
G.
Ranzi
,
M.
Santamouris
, and
M.
Kohl
, Appl. Therm. Eng.
180
, 115867
(2020
).53.
L. W.
Tseng
,
J.
Ma
,
S. J.
Wang
,
I.
Karaman
,
M.
Kaya
,
Z. P.
Luo
, and
Y. I.
Chumlyakov
, Acta Mater.
89
, 374
(2015
).54.
A. M.
Pérez-Sierra
,
J.
Pons
,
R.
Santamarta
,
P.
Vermaut
, and
P.
Ochin
, Acta Mater.
93
, 164
(2015
).55.
W.
Sun
,
J.
Liu
,
D.
Zhao
, and
M.
Zhang
, J. Phys. D: Appl. Phys.
50
(44
), 444001
(2017
).© 2024 Author(s). Published under an exclusive license by AIP Publishing.
2024
Author(s)
You do not currently have access to this content.
